GCMS DFTPP calibration report, Feb 5 2002

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Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB05\0201B.D Vial: 1 Acq On : 5 Feb 2002 10:42 am Operator: Sample : lab blank 2/1 Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 13 Bis(2-ethylhexyl) phthalate Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 31.11 0.07 ug/L 78278 Chrysene-dl2 30.50 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Bis(2-ethylhexyl) phthalate 390 C24H3804 000117-81-7 86 2 Di-(2-ethylhexyl)phthalate 390 C24H3804 000117-81-7 86 3 Bis(2-ethylhexyl) phthalate $$ 1... 390 C24H3804 000117-81-7 80 4 1,2-Benzenedicarboxylic acid, di... 390 C24H3804 027554-26-3 80 Abundance Scan 2429 (31.105 min): 0201 B.D (-) m/z 149.00 100.00% 149

5000 57 41 167 W AAA , 1 , A । . y, , , 70 113 84 207 279 30,80 31.00 31.20 3l'40 ' 1 0 ■111.......... I I m/z 33.85% lz->_____ 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #326913: Bis(2-ethylhexyl) phthalate 149

5000 167 30.80 31.00 31.20 31.40 57 71 279 m/z 167.00 29.00% 113

n/z-> OTT -H 40 60 18, 80 । । I i |l । । — r7 1, p 100 120 140 160 180 200 220 240 260 280 Abundance #326940: Di-(2-ethylhexyl)phthalate 149 TI 30.80 31,00 31.20 31.40 5000 167 m/z 41.10 21.21%

57 71|| 83 113 279

OPTT J I ..... . । | । । । । p r । ■ p l TTITTT110uTmWTTTTTTT /z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #326908: Bis(2-ethylhexyl) phthalate $$ 1,2-Benzenedicarbo... 1 I 1 ' ' 1 ' I ' ' 1 ' 1 1 1 ' 1 I 149 30.80 31.00 31.20 31.40 m/z 70.10 18.01% 5000 57 167 71 83 113 279 ° 132 O-TT tt 1 1"iibuli "i । i । P . । । 4TTEATTTTTTTTTTTTTTTTTTTET n/z—> 40 60 80 100 120 140 160 180 200 220 240 260 280 30.80 31.00 31.20 31.40

0201B.D SCAN508.M Thu Feb 21 10:18:59 2002 Page 15

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