GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB05\0201B.D Vial: 1 Acq On : 5 Feb 2002 10:42 am Operator: Sample : lab blank 2/1 Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP020702 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 Phenol-d5 Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 9.08 0.13 ug/L 87972 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenol-d5 99 C6HD5O 000000-00-0 72 2 1-Pyrrolidinecarboxaldehyde 99 C5H9NO 003760-54-1 53 3 2,5-Pyrrolidinedione 99 C4H5NO2 000123-56-8 50 4 2,5-Pyrrolidinedione (CAS) $$ Su... 99 C4H5NO2 000123-56-8 50 Abundance Scan 500 (9.082 min): 0201 B.D (-) m/z 99.10 100.00% 99

5000

71 42 93 8.80 9.00 9.20 9.40 0 ■ " i'1" I" 11 r " ■ i ‘ ■ 49 54 |' i > t1!1111J > ■ 11J •' • • | ‘ ........................ . m/z 71.00 21.90% n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #5872: Phenol-d5 99

5000 8.80 9.00 9.20 9.40 m/z 70.10 13.08% 42,50 58 66 7 ।, 01 " ■ i" " i" ■' i" ■' i ‘"11111' i111111" • i"11111" i111H'" ■ ।" " ।" " ।" “ i11111"' 111" ir" II m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #7671:1-Pyrrolidinecarboxaldehyde 43 71 99

8.80 9.00 9.20 9.40 5000 m/z 42.10 12.72%

Of ।" i" " i" " r1 ■' i “ " i"

... 11J.. I "1' I “ “ I " '11 " " i1" ‘ i m/z—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #7537:2,5-Pyrrolidinedione 56 99 8.80 9.00 9.20 9.40 m/z 41.10 12.52% 5000 27 42 70

m/z—> 0 "i""i -?5.HHH+ ।" i" " 11 11 rrn T 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 > ।" " i" ■ • i ■■ ■■ i •" ■ i ■ ■ 8.80 9.00 9.20 9.40

0201B.D SCAN508.M Thu Feb 21 10:18:57 2002 Page 6

NYC-WTC_000004789