GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB05\30644A.D Vial: 1 Acq On 5 Feb 2002 2:56 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l..-\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 1 Acetonitrile, dichloro- $$ ... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 3.49 0.07 ug/L 51779 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetonitrile, dichloro- $$ Diehl... 109 C2HC12N 003018-12-0 83 2 Acetonitrile, dichloro- 109 C2HC12N 003018-12-0 78 3 Dichloroacetonitrile $$ Acetonit... 109 C2HC12N 003018-12-0 45 4 Dichloroacetonitrile $$ Acetonit... 109 C2HC12N 003018-12-0 9 Abundance Scan 10 (3.488 min): 30644A.D (-) m/z 74.00 100.00% 74 82 5000 47 "tf 38 3.50 3.60 3.70 3.80 3.90

m/z-> ol . ......... ahov 10 20 30 40 50 60 70 1 ■ । 1 I 1 1 1 1 1 1 80 90 i ‘ । ■ 1 1 > i 1 । 100 110 m/z82.00 58.18% Abundance #11641: Acetonitrile, dichloro- $$ Dichloroacetonitrile $$... 74

5000 82 A............... 3.50 3.60 3.70 3.80 3.90 47 m/z 83.90 35.96% 35

n/z-> ol ..10p............ 20 30 bl40,. H..................1 50 60 70 'rTn 80 , 109 i ■ i ■ • • ■ i ■ ■ ■ ■ i ■ ■ 90 100 110 Abundance #11644: Acetonitrile, dichloro- 74 35 3.50 3.60 3.70 3.80 3.90 5000 82 m/ z 76.00 31.03% 47

m/z-> 0+ ■ ■ । 10 > I 1 । ‘ । । ■ 1' । 20 30 40 50 analpua 60 _______________ L ’[’ ’’IU 70 80 90 TIit 1 ■ i > ■ • ■ । 100 । 1 j ■ ■ 110 Abundance #11642: Dichloroacetonitrile $$ Acetonitrile, dichloro- 74 3.50 3.60 3.70 3.80 3.90 82 m/z 47.00 29.85%

5000 47 35

/z-> 0 ----- - 10 12 20 30 40 —TT 50 60 70 T-p 80 । 108 I ' I ' 1 1 1 I 1 1 1 1 I 1 1 90 100 110 AMAA 3.50 3.60 3.70 3.80 3.90

30644A.D SCAN508.M Fri Feb 22 11:44:23 2002 Page 3

NYC-WTC_000004902