Analytical laboratory reports attachment for PCDDs and PCDFs, 2008

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’ i 3 IW "z Pace Analytical SarvicBS, Inc. 1700 Elm Street. .Suite 200 ^ace Analytical '; Minneapolis, MN 55414 Phone: 612.807.1700 emw.pacelabs.com RETORT OF: CHEMICAL ANALYSES Fax: 612.607.6444

1 PROJECT: PCDD/PCDF ANALYSES DATE: January 9, 2002

PAGE: 5 REPORT NO: 01-1052682 i @ PCDD/PCDF Quantification and Calculations (Cont.) Each pair of ion mass peaks in the selected-ion-current chromatograms was evaluated manually to Q determine if it met the criteria for a PCDD or PCDF isomer. Areas of all peaks exhibiting correct ion Ji ratios, having, Tetention times within the correct windows, and having areas corresponding to concentrations''" in the range covered by the initial calibration were then summed for calculations of total congener concentrations. The toxic equivalence of each sample was calculated using the factorsjlsted in Table 5.

limit of detection (LOD) based on producing a signal that is 2.5 times the noise level, was calculated for each undetected 2,3,7,8-substituted isomer of any tetra through octa chlorinated congener class. The noise heights used to calculate the detection limits were measured at the M retention time of the specific isomer. The formula used for calculating the LOD is: iai Hn X Qis X 2.5 LOD = La His X W X Rf where: • 3 LOD = Single isomer limit of detection Hn = Sum of noise heights at native isomer retention time Qis = Quantity of labeled internal standard His = Sum of peak heights for labeled internal standard Sample amount

I = Response factor

, , The recovery of the 2,3,7,8-TCDD-®’Cl4 enrichment efficiency standard and each ’^Cij-labeled Ji internal standard, relative to either 1,2,3,4-TCDD-’^C,2 or 1,2,3,7,8,9-HxCDD-^^Ci2, was calculated using the following equation:

I %R = Ais X Qrs X 100%

Rfr X Ars x Qis ra where:

, %R = Percent recovery of labeled internal standard ! Ais = Sum of integrated areas of labeled internal standard Qrs = Quantity of recovery standard - Ars = Sum of integrated areas of recovery standard f Rfr = Response factor of the specific labeled internal standard relative to the recovery standard Qis = Quantity of the labeled internal standard congener added to the sample

j REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc.

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