Chain of Custody Form Instructions for WTC Building Sampling

NYC 9/11 Public Portal Document

V All analyses were done on a volunteer basis and will be available as public documents. We report today on the data from Oct. 2 through Oct. 31, 2001. Airborne particles and human health In general, there are myriad ways that materials released into the air can affect human health. What the particles are made of matters; so do size, shape and quantity. The DELTA team analyzed the samples for the unique chemical and physical signatures of dozens of substances, including elements from concrete and glass, such as silicon; from burning fuel oil, such as sulfur, vanLdium and nickel; and from burning computers and electrical systems, such as lead. They also looked for organic, or carbon-based, compounds from burning wood, plastic and carpets. And they tested for glass shards and asbestos. Some of these materials are known to cause health problems in some people when they are inhaled in sufficient amounts. Sulfur, for example, can irritate lung tissues. Lead can damage the central nervous system. Some carbon-based compounds can cause cancer. So can the mineral asbestos. Just as the composition of inhaled particles can affect health, so can size. The team analyzed the particles by size in eight ranges from coarse (12 micrometers to 5 micrometers in diameter) to very fine (0.24 micrometers to 0.09 micrometers in diameter). Most of the uitrafine mode (particles less than 0.1 micrometers) was not collected. Coarse particles are typically filtered by the nose or coughed out of the throat and upper lungs. They can irritate the mucous membranes, causing coughs and nosebleeds. In some individuals, they can cause allergic reactions such as dry eyes; nose, throat and skin irritation; coughing, sneezing and respiratory distress. They can also cause breathing problems or aggravate pre­ existing breathing problems, such as asthma. However, very fine particles can travel deep into human lungs. Such small particles may have no immediate apparent health effects in moderate concentrations, but they typically are removed from the lungs through the bloodstream and heart, increasing the possibility of health impacts. There are no established safe limits for inhaled very fine particles. The closest reference is the U.S. EPA “PM2.5” standard, which limits the allowable mass of airborne particles in the size range 2.5 micrometers to 0 micrometers. That standard is based on health studies of typical air samples, in which very fine particles are a small fraction of the total mass. In contrast, in the World Trade Center samples analyzed at UC Davis, the very fine particles are a large fraction of the total mass. In a news conference today, the DELTA researchers described key findings in these categories: very fine particles, coarse particles, metals, asbestos and glass. Very fine particles There were numerous events when bursts of wind lasting six to eight hours carried unprecedented amounts of very fine particles to the sampling site. In the largest spike, the DELTA Group analysis found 58 micrograrr.s per cubic meter of very fine particles in one 45-minute period—“an extremely high peak,” Cahill said. Cahill said the very fine particles contained high levels of suffur and sulfur-based compounds, which in early analyses appear to have been ** .. .nated by sulfuric acid. The very fine particles also contain high levels of very fine silicon, potentially from the thousands of tons of glass in the debris. Cahill noted that even those large amounts were likely to be smaller than those present at Ground Zero and some other parts of Lower Manhattan, since weather data show that typically only part of the dust clouds traveled directly over the sampling site.

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