NYC 9/11 Public Portal Document
Chlorinated Dioxins and Furans (CDD/CDF)
Several different CDD/CDF data sets were found in the NYC Response database, including
individual congeners, PCDD/PCDF, Dioxins, and TEQ (toxic equivalents). CDD/CDF isomer or
congener-specific samples in the NYC Response database include seven (7) bulk dust samples and six
(6) water samples. The bulk dust samples are all from the Battery PK & 2"d Pl location taken on
September 16``'. The water samples appear to be from various treatment locations of the Newtown Creek
STP taken on September 15'. In the water samples, 2,3,7,8-TCDD was not detected with an MDL of
0.01 ng/L (ppt). As of November 16"', no additional CDD/CDF sample results have been found in the
NYC Response database.
The results from four (4) CDD/CDF bulk dust samples taken on September 16°i at the Battery Pk &
2"d Pl sampling site are summarized in Table 10 and Figure 7. At the time of this Draft Report, no
additional data has been posted in the NYC Response database. From the bulk dust results, the pattern
in CDD/CDF congeners and congener class concentrations in the different samples are highly correlated
suggesting a single source. The correlation coefficient calculated between samples AO6353 and
AO6351 using the data in Table 3 is 0.9726. In each of the four samples, CDD concentrations generally
increase with the level of chlorination. In three of the four samples, OCDD is approximately ten times
(1 Ox) the concentration of total TCDD. The reverse is true of CDF concentrations where the
concentration decreases with the level of chlorination. In all four samples, the concentration of OCDF is
approximately one-tenth (1/10) the concentration of total TCDF. The highest reported concentration of
2378-TCDD, the most toxic CDD/CDF, was 5.18 pg/g (ppt).
Comparing the Battery Pk & 2"d Pl bulk dust CDD/CDF profile to nine (9) references in
Chemosphere, 1990, Vol 20, which includes CDD/CDF profiles for urban and background soil, paper
pulp, incinerator fly ash, and others, the best correlation is with samples from a paper and oil incinerator
described by Brown, et. al. Q. 1785 - 1791), with a correlation coefficient of 0.9464.
PCDD/PCDF is also reported for sediment, bulk dust, air, and water samples. All of the sixteen (16)
sediment samples were taken at the Foot of Vesey BY CSO M-6 location on September 15'. The
highest concentration of PCDD/PCDF reported for the sediment samples was 39.9 pg/g (ppt).
Six (6) PCDD/PCDF bulk dust samples from the WTC location (no sample date listed) were also
reported with a high value of 84.4 pg/g (ppt).
From five (5) water samples taken on September 16t , with no location listed, the highest
PCDD/PCDF value reported was 0.016 ng/L (ppb).
Four (4) PCDD/PCDF air samples were also reported for samples taken on September 16"' from four
(4) different locations on Lower Manhattan. The highest reported PCDD/PCDF value in the air samples
was 0.066 ng/m3 from the Location B - Church St & Dey St site. The PCDD/PCDF values are the same
as the TEQ values also reported for the same four (4) sites from September 16'''.
Page 35 of
NYC-WTC-000130476
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