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GCMS analysis results, sample AD24048, October 29, 2001

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Gas chromatography-mass spectrometry analysis of environmental sample AD24048 conducted on October 29, 2001, identifying unknown compounds.

NYC-WTC_000067840–000067854

Folder label: “GCMS Scan X 10/5/01 An 10/25/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\OCT2501\24048.D Vial: 9 Acq On : 25 Oct 2001 8:30 pm Operator: 209 GALOS Sample : gc/ms unknown Inst ; GC/MS 209 Mise Multiplr; 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\NP101901.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 5 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 7.72 1.58 ug/i 266876 1,4-Dichlorobenzene-d4 11.73 Hit# of 5 tntative ID MW MolForm CAS# Qual 1 2-Pentanop;e, 4-hydroxy-4-methyl- 116 C6H12O2 000123-42-2 40 2 2-Propanol, 2-methyl- 74 C4H10O 000075-65-0 12 3 Acetoi^ 58 C3H60 000067-64-1 9 4 Morpholine, 4-methyl- 101 C5H11NO 000109-02-4 9 Abundance Scan 292 (7.721 min): 24048.D (-) m/z 42.95 100.00% 4)3

59 5000 101 _____ J - ' * 7.^' ‘7.6O 7.80 'ab6 “ ' ‘ 3?| + 69 83 m/z 59.05 53773% ' I ‘ ‘ ' I ' ’ ' ' 1 ' ' ' I ' ' ' ' I ' ' ' ' I ' • • I I I • ' I I ■ 10 20 30 40 50 60 70 80 90 100 110 Abundance #64275: 2-Pentanone, 4-hydroxy-4-methyl- 43

5000 ’ ' ' I ‘ ' I ' ‘ ‘ ' 1 ' ■ T 59 7.40 7.60 7.80 8.00 m/z 100.95 22.93% 15 31 101 , I TT-r-r-ir r-j-r-r-r-T-f-T -r+ I ' ' I ' J , I I, , , • 1 • ■ • • I • • ■ ■ I ■ ■ ■ • 1 • • • • I • ■ ■ < I • ■nfe-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #62572; 2-Propanol, 2-methyl- 50 7.40 7.60 7.80 8.00 19.33%

.. L 5000- 31 41

' I ‘ ■ 1 ‘ ■ I ' ‘ • I ' ■ ' ' I ' ' ' ' I ‘ ■nfe-> 10 20 30 40 50 60 70 80 90 100 110 <M3undance #62322: Acetone 40 7.40 7.60 7.80 8.00 m/z 41.05 8.49% 5000 58 27

Tlfe-> 10 20 30 40 50 60 70 80 90 100 110 7.40 7.60 7.80 8.00

24048.D NP101901.M Fri Oct 26 10:21:09 2001 Page 5

NYC-WTC_000067852

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NYC-WTC_000067852Source: NYC Law Department, mirrored locally

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