GCMS calibration results, sample AE05238, March 2002

NYC 9/11 Public Portal Document

Quantitati report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\031602\CAj D Vial: 2 Acq On : 16 Mar 2002 10:04 am Operator: McLean Sample : 4 Ox Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 20 08:36:31 2002 Quant Results File: 5080302.RES

Quant Method C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title Quantitation For Method 508gcscan Last Update Thu Mar 14 13:02:27 2002 Response via Initial Calibration DataAcq Meth 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.56 150 2157435 20.00 Ug/L 0.00 10) Naphthalene-d8 13.04 136 5042231 20.00 ug/L 0.02 17) Acenaphthene-dlO 18.15 164 2694477 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.51 188 4493901 20.00 ug/L 0.02 38) Chrysene-dl2 30.34 240 3767263 20.00 ug/L 0.02 44) Perylene-dl2 34.20 264 2072924 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 0.00 235 Od 0.00 ug/L Spiked Amount 5.000 Recovery - = 0.00%

Target Compounds ' Qvalue 2) N-nitroso-dimethyl amine 3.57 74 1903055 39.28 ug/L 100 3) bis(2-chloroethyl) ether 9.02 93 2848944 37.31 ug/L 98 4) 1,3 - Dichlorobenze 9.39 146 2842218 37.63 ug/L 100 5) 1,4 - Dichlorobenzene 9.61 146 2827689 37.54 ug/L 100 6) 1,2 - Dichlorobenzene 9.98 146 2608937 37.41 ug/L 100 7) 2,2 ' - oxybis (1-Chloropr 10.45 45 6522769 37.50 ug/L 98 8) N-Nitroso-di-n-propylamine 10.81 70 2194295 39.96 ug/L 99 9) Hexachloroethane 10.87 117 1125336 39.77 ug/L 99 11) Nitrobenzene 11.14 77 3511924 38.67 ug/L 99 12) Isophorone 11.86 82 6450563 38.60 ug/L 100 13) bis(2-Chloroethoxy) methan 12.59 93 3872320 38.50 ug/L 99 14) 1,2,4-Trichlorobenzene 12.92 180 2225454 38.55 ug/L 100 15) Naphthalene 13.11 128 7988473 38.12 ug/L 99 16) Hexachlorobutadiene 13.54 225 1287191 39.87 ug/L 98 18) Hexachlorocyclopentadiene 15.61 237 1083753 45.68 ug/L 98 19) 2-chloronaphthalene 16.54 162 4868005 39.58 ug/L 100 20) Dimethylphthalate 17.64 163 5855563 39.88 ug/L 99 21) 2,6-Dinitrotoluene . 17.74 165 1242664 39.77 ug/L 98 22) Acenaphthylene 17.72 152 6680242 39.15 ug/L 99 23) Acenaphthene 18.25 153 4585090 39.52 ug/L 99 24) 2,4-Dinitrotoluene 18.90 165 1812074 40.50 ug/L 99 25) Diethylphthalate 19.77 149 5085296 40.25 ug/L 100 26) 4-Chlorophenyl-phenyl ethe 19.92 204 2620135 38.91 ug/L 99 27) Fluorene 19.79 166 5270464 38.53 ug/L 100 28) Azobenzen/ 1,2-Diphenylhyd 20.38 77 7250866 38.91 ug/L 100 30) N-Nitrosodiphenylamine 20.31 169 3705943 38.37 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.34 248 1520366 38.33 ug/L 98 32) Hexachlorobenzene 21.38 284 1574590 37.63 ug/L 93 33) Phenanthrene 22.60 178 7862815 37.78 ug/L 99 34) Anthracene 22.74 178 7776737 37.65 ug/L 100 35) Di-n-butylphthalate 24.67 149 9283177 38.92 ug/L 100 36) Fluoranthene 26.10 202 9228768 39.02 ug/L 96 39) Pyrene 26.72 202 9394509 36.07 ug/L 96 40) Butylbenzylphthalate 29.07 149 4169140 37.39 ug/L 93 41) Benzo (a) antracene 30.31 228 7699524 38.94 ug/L 100 42) Bis (2-ethylhexyl) phthala 30.93 149 5435454 36.87 ug/L 98 43) Chrysene 30.42 228 7259136 38.64 ug/L 99 45) Di-n-Octylphthalate 32.78 149 9111241 40.92 ug/L 97 46) Benzo (b) fluoranthene 33.26 252 6051873 41.43 ug/L 99

(#) = qualifier out of range (m) = manual integration CAL40XA.D 5080302.M Wed Mar 20 08:38:00 2002 Page 1

NYC-WTC_000059037