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Sample AD28044 Method 525.2 analysis, Jan 2002

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Laboratory results for sample AD28044 analyzing pesticides and organic contaminants using Method 525.2.

NYC-WTC_000055427–000055432

Folder label: “525 X 11/21/01 A 12/11/01 + REANALYSIS 1/25/02

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NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

. Data File : C:\MSDCHEM\l\DATA\012502A\28044RR.D Vial: 9 Acq On Sample Mise : 25 Jan 2002 : REINJ : 8:40 pm

MS Integration Params: rteint.p Operator: Inst Multiplr: : McLean Instrumen 1.00 - - -date Quant Time: Jan 28 12:00:00 2002 Quant Results File: 012402B.RES

Quant Method : C:\MSDCHEM\1\5973N\012402B.M (RTE Integrator) Title : Quantitation For Method 525.2 Last Update : Fri Jan 25 11:19:14 2002 Response via : Initial Calibration DataAcq Meth : 012402DF

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) Acenaphthene-diO 17.96 164 13784572 5.00 ug/L 0.00 9) Phenanthrene D-10 22.27 188 18310001 5.00 ug/L 0.00 20) Chrysene D-12 30.03 240 11263677 5.00 ug/L 0.00

System Monitoring Compounds 2) 1,3-Dimethyl-2-nitrobenzen 12.89 134 2500677 3.54 ug/L 0.00 Spiked Amount 5,000 Recovery = 70.80% 19) Triphenyl Phosphate 29.33 326 2726487 4.94 ug/L 0.00 Spiked Amount 5.000 Recovery = 98.80% 21) Perylene D-12 34.02 264 6437535 4.02 ug/L 0.00 Spiked Amount 5.000 Recovery = 80.40%

Target Compounds Qvalue 3) Hexachlorocyclopentadiene 0.00 237 0 N.D. d 4) Hexachlorobenzene 21.13 284 13358 0.02 ug/L 85 5) EPTC 15.67 128 6185 N.D. 6) 2,6-Dinitrotoluene 0.00 165 0 N.D. d 7) 2,4-Dinitotoluene 18.71 165 30279 0.94 ug/L 45 8) Molinate 18.90 126 19853 Below Cal # 1 10) Simazine 0.00 201 0 N.D. d 11) Atrazine 0.00 200 0 N.D. 12) Alachlor 23.30 160 5524 0.15 ug/L 78 13) Terbacil 0.00 161 0 N.D. d 14) Acetochlor 0.00 146 0 N.D. 15) Metribuzin 0.00 198 0 N.D. 16) Metolachlor 24.58 162 5480 0.22 ug/L 84 17) Butachlor 0.00 160 0 N.D. d 18) 4,4'-DDE 0.00 246 0 N.D. d 22) Bis (2-Ethylhexyl) adipate 29.32 129 48009 0.53 ug/L 22 23) Bis (2-Ethylhexyl) phthala 30.70 149 279643 0.49 ug/L 100 24) Benzo (a) pyrene 0.00 252 0 N.D. d

(#) = qualifier out of range (m) = manual integration 28044RR.D 012402B.M Mon Jan 28 12:08:50 2002 Page 1

NYC-WTC_000055430

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NYC-WTC_000055430Source: NYC Law Department, mirrored locally

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