GCMS surrogate recovery results for sample AE00281, Jan 2002

NYC 9/11 Public Portal Document z oealti compound Report Data File C:\MSDCHEM\l\5973N\02JAN09\281.D Vial: 6 Acq On 9 Jan 2002 10:21 pm Operator: Sample 508 scan ext 1/7 Inst : Instrumen Mise January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ******************************************************************* ** Peak Number 6 3-Penten-2-ol $$ .alpha.,.g... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 5.70 0.13 ug/L 73242 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Penten-2-ol $$ .alpha.,.gamma... 86 C5H10O 001569-50-2 59 2 3-Penten-2-ol 86 C5H10O 001569-50-2 42 3 3-PENTEN-2-OL, (Z) - 86 C5H10O 024652-50-4 42 4 methyl 2-oxo-3-methylbutanoate 130 C6H10O3 000000-00-0 38 Abundance Scan 204 (5.703 min): 281 D (-) m/z 41.10 100.00% 41 71

5000

45 ----------A--- 38 51 55 58 67 84 5.40 5.60 5.80) 6.00 m/z-> 0 mpg + 20 25 30 35 40 ).. MaAolpoapa] 45 50 55 60 65 70 hg 75 80 85 90 95 m/ z 43.10 83.37% Abundance #4047:3-Penten-2-ol $$ alpha...gamma.-Dimethylallyl alco... 43 71

5000 39 TT ■ i ■ r' ' i ' ' ■ ’ i ' 1 ‘ ' I

27 53 5.40 5.60 5.80 6.00 67 m/ z 71.10 75.69% 58 86

/z-> -H+ 50 H 01 111''1' I' 20 25 TI‘ 49 TTTTTT 55 60 65 70 75 80 85 90 95 30 35 40 45 ।1' 1111111 ■ ■11'r'11 ■1111 ■

Abundance #4046: 3-Penten-2-ol 71 43 ' ' ' i ''T ■ H ‘ ■ 'i ■ T 5.40 5,60 5.80 6.00 5000 39 rn/z 69.10 48.35% 53 67 27

m/z-> 01 T‘4‘‘‘‘I TTTTTH T'IT MU Im eeH mmPP 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 l 58 86

Abundance #4208:3-PENTEN-2-OL, (Z)- 71 5.40 P/S5.801* 5.60 6.00 43 m/z 39.10 45.53%

X 5000 39 53 67 27

n/z-> 0 TIT‘3 1' 11 TTTTTH 20 25 30 35 40 ++ 45 ' ’ I'' 50 58 • i1 ■1 ■ । ■ 55 60 —65l70 75 80 85 90 ‘9513 5.40 r 5.60 5.80 6.00

L.D SCAN508.M Thu Jan 10 11:52:00 2002 Page 8

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