GCMS surrogate recovery results for sample AE00277, Jan 2002

NYC 9/11 Public Portal Document Data File : C: \MSDCHEM\1\5973N\02JAN09\277.D Vial: 2 Acq On 9 Jan 2002 6:59 pm Operator: . Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L Peak Number 2 PROPANE-1,1,1,3,3,3-D6 Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 3.76 0.14 ug/L 59340 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 PROPANE-1,1,1,3,3,3-D6 50 C3H2D6 002875-96-9 9 2 2-Butyne-1,4-diol 86 C4H602 000110-65-6 5 3 4,4-DI-TRIDEUTEROMETHYL-2-ALLYLC... 172 C11H12D6O 000000-00-0 4 4 Boron trifluoride etherate $$ Bo... 142 C4H10BF3O 000109-63-7 4 Abundance Scan 34 (3.762 min): 277.D (-) m/z 43.00 100.00% 43

n/z-> 5000

Of - 49 84

■ I 11 I | । ' ' ' | ' ■ ' • i ■ ■ ■ ■ i ■ ' 4 1 i ■ 1 1 ' | ■ ■ ■ ■ i ■ ■ । T’ 11 1 11 1 ' I m/z 3.60 49.00 N 3.80 4.00 46.30% 4.20

Abundance 20 25 30 35 40 45 50 55 #230: PROPANE-1,1,1,3,3,3-D6 60 65 70 75 80 85 90 95 AMWWAMWW 33 49 wW 5000 ■' d • I ' • ■ ■ l ■ ■ ’ ■ I ■ ‘ ‘ 4 l ■

A 3.60 3.80 4.00 4.20 42 45 m/z 83.90 36.75% 33

m/z--> 01 20 1 i' ' '' i ' 25 30 A— ll 35 38

40 -T‘r1211111111211111111CEtN‘T‘tF"tt‘orrr"T 45 50 55 60 65 70 75 80 85 90 95 Abundance #3821: 2-Butyne-1,4-diol 29 39 57

3.60 3.80 4.00 4.20 5000

51 68 AAMMNV m/z 86.00 24.81%

/z-> 0 T-rT-m-r-p- 111' H.. mAlr 86 TTTTTTTT ■ i' ■ ■ ■ i ■ ■ ■ ■ i ■'' ■ i1 ■' • i ■ ■1 ■ । 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #68402: 4.4-DI-TRIDEUTEROMETHYL-2-ALLYLCYCLOHEXANONE 4h 3.60 3.80 4.00 4.20 44 m/z 51.00 11.60%

5000

47 mMyMy . 0 n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20

277.D SCAN508.M Thu Jan 10 11:51:36 2002 Page 4

NYC-WTC_000050846