GCMS analysis results for sample AE00168, Jan 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN24\00168.D Vial: 1 Acq Oh : 24 Jan 2002 2:59 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 24, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1.. .\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 9 4-HYDROXY-BICYCLO[2.2.2]OCT... Concentration Rank 11

R.T. EstConc Area Relative to ISTD R.T.

16.55 0.05 ug/L 30979 Acenaphthene-dl0 18.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-HYDROXY-BICYCLO[2.2.2]OCTANONE... 140 C8H12O2 066348-59-2 38 2 IH-cyclobuta[de]naphthalene $$ C... 140 C11H8 024973-91-9 9 3 4,4,5,5-tetramethylcyclopentan-1... 140 C9H160 111689-30-6 9 4 2-Dimethylamino-4 ,5-dimethyl-oxa... 140 C7H12N20 000000-00-0 9 Abundance Scan 1154 (16.549 min): 00168. D (-) m/z 140.10 100.00% 140

5000 .................... )........... .. 71 122 172 43 56 16.20 16.40 16.60 16.80 1 miz-> TTI’ - 89 1 • l ‘ 4 4 • I • ’ ‘ ‘ I ‘ ‘ ‘ ‘ I • • ‘ • I ‘ ‘ ‘4 I 40 50 60 70 80 90 100 110 120 130 140 150 160 170 ■ ■ ।w■ i' ■ ■ ■ । m/z 172.20 27.88% Abundance #35653:4-HYDROXY-BICYCLO[2.2.2]OCTANONE $$ Bicyclo[2.2.2]... 83 VO 55 70 97 112 5000 16.20 16.40 16.60 16.80 m/z 122.10 27.42% 125 l * *’• ' I ‘ ' •111 • i ■ • ■ • i ■' i ■ ■ • ■ i •'1 ■ i ■ ■1 ‘ i ■ miz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #36659:1 H-cyclobuta[de]naphthalena $$ Cyclobuta dejnaphth... 140 16.20 16.40 16.60 16.80 ' 5000 m/z 71.10 26.00%

89 113

miz-> ■ “ i " ' ■ i •' ■ • i ■ 40 50 60 70 80 fl ■ i1 ■ ■ ■ i ■ ‘ " t e 90 100 110 120 130 140 150 160 170 1’1+11’1114’1/411411 — Abundance #36234:4,4,5,5-tetramethylcyclopentan-1-one 140 16.20 16.40 16.60 16.80 ' ‘ ‘ 70 m/z 43.10 22.44%

Muu 83 5000 125

55 97 107 *•i*,, ।।(.. >. ।. —pr 1 ‘ i1 ■1 ■ i ■ " ■ i ■ ■ ■ ■ i1 ’iF /z—> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 16.20 16.40 16.60 16.80

00168.D SCAN508.M Fri Jan 25 10:25:53 2002 Page 11

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