GCMS reference standard results, Sample AE05750, April 2002

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Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\APR1202\REFA2.D Vial: 18 Acq On : 16 Apr 2002 12:45 am Operator: Sample : gc/ms scan 4/10 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 17 9:35 2002 Quant Results File: GCMS0412.RES

Quant Method C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title 209 625/TCLP calibration table Last Update Tue Apr 16 14:55:12 2002 Response via Initial Calibration DataAcq Meth GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.23 152 505510 20.00 ug/1 0.00 10) Naphthalene-d8 15.87 136 1873840 20.00 ug/1 0.00 17) Acenaphthene-diO 21.17 164 1076752 20.00 ug/1 0.00 30) Phenanthrene-dlO 25.62 188 1553054 20.00 ug/1 0.00 39) Chrysene-dl2 33.67 240 1005828 20.00 ug/1 0.00 45) Perylene-dl2 37.90 264 657562 20.00 ug/1 -0.02

System Monitoring Compounds 2 8) TCMX 23.31 209 46293 8.58 ug/L -0.02 Spiked Amount 10.000 Recovery = 85.80% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.88 74 103578 9.41 ug/1 99 3) bis(2-Chloroethyl)ether 11.62 93 249291 14.56 ug/1 99 4) 1,3-Dichlorobenzene 12.13 146 208125 11.79 ug/1 99 5) 1,4-Dichlorobenzene 12.28 146 219357 12.34 ug/1 100 6) 1,2-Dichlorobenzene 12.79 146 215225 13.04 ug/1 99 7) 2,21-oxybis(1-Chloropropan 13.11 45 347723 14.70 ug/1 99 8) N-Nitroso-di-n-propylamine 13.50 70 160312 14.27 ug/1 99 9) Hexachloroethane 13.64 117 57402 8.82 ug/1 97 11) Nitrobenzene 13.91 77 215686 13.13 ug/1 97 12) Isophorone 14.55 82 376929 12.13 ug/1 99 13) bis(2-Chloroethoxy)methane 15.24 93 297657 14.70 ug/1 100 14) 1,2,4-Trichlorobenzene 15.75 180 191806 13.47 ug/1 98 15) Naphthalene 15.92 128 662858 14.71 ug/1 100 16) Hexachlorobutadiene 16.46 225 54235 7.61 ug/1 94 18) Hexachlorocyclopentadiene 18.66 237 7921 1.66 ug/1 97 19) 2-Chloronaphthalene 19.43 162 407674 14.36 ug/1 98 20) Dimethylphthalate 20.51 163 519024 15.85 ug/1 99 21) 2,6-Dinitrotoluene 20.73 165 102365 13.08 ug/1 99 22) Acenaphthylene 20.70 152 601528 15.14 ug/1 99 23) Acenaphthene 21.26 153 433375 15.35 ug/1 99 24) 2,4-Dinitrotoluene 21.90 165 128463 12.47 ug/1 99 25) Diethylphthalate 22.65 149 508640 16.20 ug/1 99 26) 4-Chlorophenyl-phenylether 22.80 204 231804 16.64 ug/1 99 27) Fluorene 22.78 166 477151 15.95 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.27 77 439277 13.22 ug/L 97 31) N-Nitrosodiphenylamine 23.19 168 156881 12.14 ug/1 99 32) 4-Bromophenyl-phenylether 24.27 248 126978 16.84 ug/1 97

(#) = qualifier out of range (m) = manual integration REFA2.D GCMS0412.M Wed Apr 17 09:37:34 2002 Page 1

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