GCMS reference standard results for volatile organics, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\020403\0402REFl.D Vial: 11 Acq On 3 Apr 2002 6:17 pm Operator: Nefliu Sample 04/02 ref Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 04 08:40:10 2002 Quant Results File: SCAN020403.RE

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020403.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Thu Apr 04 08:40:00 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 10.66 152 2924073 20.00 ug/1 0.00 10) Naphthalene-d8 15.77 136 10666191 20.00 ug/1 0.00 17) Acenaphthene-diO 23.66 164 6182104 20.00 ug/1 0.00 31) Phenanthrene-dlO 30.90 188 10196970 20.00 ug/1 0.00 39) Chrysene-dl2 39.11 240 9754443 20.00 ug/1 0.00 45) Perylene-dl2 42.31 264 6507129 20.00 ug/1 0.00

System Monitoring Compounds 2 8) TCMX 26.73 207 254745 4.21 ug/1 0.00 Spiked Amount 5.0 Recovery = 8420% Target Compounds 7 Qvalue 2) N-nitrosodimethylamine 3.63 74 344725m 4.26 ug/1 3) bis(2-Chloroethyl)ether 9.94 93 1290571 8.47 ug/1 99 4) 1.3-Dichlorbenzene 10.40 146 1236018 5.89 ug/1 99 5) 1,4-Dichlorobenzene 10.72 146 1302888 6.13 ug/1 99 6) 1,2-Dichlorobenzene 11.23 146 1295683 6.46 ug/1 98 7) 2,2'oxybis(1-Chloropropane 12.04 45 1012022 9.95 ug/1 99 8) N-Nitroso-di-n-propylamine 12.51 43 712289 8.37 ug/1 99 9) Hexachloroethane 12.52 119 309333 4.68 ug/1 98 11) Nitrobenzene 12.92 77 1062099 7.09 ug/1 100 12) Isophorone 14.03 82 1926496 6.98 ug/1 98 13) bis(2-Chloroethoxy) methan 15.25 93 1560147 8.61 ug/1 100 14) 1,2,4-Trichlorobenzene 15.61 180 1143116 6.77 ug/1 99 15) Naphthalene 15.85 128 4186792 8.19 ug/1 100 16) Hexachlorobutadiene 16.62 225 398465 4.21 ug/1 97 18) Hexachlorocyclopentadiene 19.79 237 47765 0.87 ug/1 89 19) 2-Chloronaphthalene 21.13 162 2621433 7.73 ug/1 99 20) Acenaphthylene 22.95 152 3655380 7.71 ug/1 99 21) Dimethyl phthalate 23.04 163 3232020 8.80 ug/1 99 22) 2,6-Dinitrotoluene 23.15 77 119120 8.72 ug/1 93 23) Acenaphthene 23.79 153 2834996 8.29 ug/1 100 24) 2,4-Dinitrotoluene 24.92 165 454429 8.62 ug/1 97 25) Fluorene 26.20 166 3230031 8.30 ug/1 100 26) Diethyl phthalate 26.41 149 3080025 8.72 ug/1 99 27) 4-Chlorophenyl-phenylether 26.53 204 1546841 8.20 ug/1 98 29) N-Nitrosodiphenylamine 27.13 168 1011526 7.01 ug/1 99 30) Azobenzene 27.21 77 2716401 7.96 ug/1 100 32) Hexachlorobenzene 28.77 284 1142265 8.05 ug/1 99 33) 4-Bromophenyl-phenylether 28.89 248 918531 7.94 ug/1 98 34) Phenanthrene 30.99 178 4885090 8.69 ug/1 100 35) Anthracene 31.22 178 4249578 7.73 ug/1 100

(#) = qualifier out of range (m) = manual integration 0402REF1.D SCAN020403.M Thu Apr 04 08:40:59 2002 Page 1

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