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GCMS blank analysis results for volatile organics, May 2002

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Laboratory report showing blank sample analysis results for volatile organic compounds using gas chromatography-mass spectrometry on May 9, 2002.

NYC-WTC_000044858–000044872

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\430LB.D Vial : 12 Acq On 9 May 2002 12 :22 am Operator: Mclean Sample 4/30 eh Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 2 3-Oxetanol, 2,2,3-trimethyl- Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

7.73 0.23 ug/L 270677 1,4-Dichlprobenzene-d4 9.94

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Oxetanol, 2,2,3 -trimethyl- 116 C6H1202 025910-96-7 2 2-Hexanone, 5-methyl- 114 C7H140 000110-12-3 25 3 2-Hexanone, 5-methyl- 114 C7H140 000110-12-3 25 4 5-Hexen-2 -one 98 C6H10O 000109-49/9 9 Abundance Scan 792 (7.733 min): 430LB.D (-787) (-) m/z 43.10 100.00%

U 43

5000 58 ~AAAW 87 । । । i iii । । । । । । > r f r T i । i-1 । 98 7.40 7.60 7.80 800 0 +-r 51 |,| | — m/z 58.10 34.87% |■|■'“>“' ' । । ‘ "H ‘ 1 1 ‘ ' T1 1‘l |‘ m/z--> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #5761:3-Oxetanol, 2,2,3-trimethyl-

5000 43

58 WA/WAA/w ■ 1 । ■ 1 1 1 i 1 1 1 ■ । ■ ' ■ ■ । 1 1 1 ' i 7.40 7.60 7.80 a 8.00 29 71 m/z 8 7.10 21.08% 86 0- ....... . 11,371, +-, 54.41—65441—— I ' I > I I I I I ' I I I I 1 I I I I 79 ,| 98 11-11............... n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #5735: 2-Hexanone, 5-methyl- 43 ......... .... ..... 1 I I I I I I I I ’ I I I I 1 > I I I I I I I I

7.40 7.60 7.80 8.00 5000 m/z 98.0 0 12.65% 58 15 27 .......... . 51 I 1 65 71 81 99 114 0- —TT ' I [ i i I i । i i । i ।11 n । । । ii ।' । । i । । । ।— I i i' [ । । ..... J....... । । । । । । । । । । । v । i । i । r m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #109705: 2-Hexanone, 5-methyl- 4t3 7.40 7.60 7.80 8.00 m/z 41.10 11.89%

5000 58 27

/z-> 0 ..... I... || 10 20 30 40 PTTT 50 J l........ 71 ......... 85......... 99......... 114 11।1111।1111।■11' r1।। । । 1 । । ' । * । । । । । 60 70 80 90 100 110 120 | 7.40 7.60 7.80 8.00

430LB.D 050102.M Thu May 09 13:30:06 2002 Page 5

NYC-WTC_000044868

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NYC-WTC_000044868Source: NYC Law Department, mirrored locally

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