GC/MS calibration table, sample AE08837, April 2002

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Data File : C:\HPCHEM\l\DATA\APR2302\8837.D Vial: 6 Acq On : 23 Apr 2002 7:18 pm Operator: Sample : gc/ms scan 4/15 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library- : C:\DATABASE\NBS75K.L **************************************************** * * * ********* * * *** Peak Number 4 Butane, 2,3-dichloro-2-methyl- Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

7.73 0.77 ug/1 110633 1,4-Dichlorobenzene-d4 12.22

Hit# of 5i Tentative ID MW MolForm CAS# Qual -1----------------------- 1 Butane, 2,, 3 -dichloro-2 -methyl - 140 C5H10C12 000507-45-9.90 2 Acetic cid, chloro-, anhydride 170 C4H4C12O3 000541-88-8 25 3 Propan 2-bromo-l-chioro- 156 C3H6BrCl 003017-95-6 23 4 1-Propene, 2-chloro-____________ 76 C3H5C1 000557-98-2 14 Abundance * Scan 292 (7.726 min): 8837.D (-) m/ z 76.95 100.00% 77 41

5000

i । । । । । । । । , A i' । । । । । - 1 1 i ' 53 63 105 7.40 7.60 7.80 8.00 127 207 89 11 mt I ,,i l,i . 1,, I, . r "11 1"' r I [ I l t I | i । i r | i I I I I I I I I I I I I I I I I I i" " i " " I m/ z 41.05 67.72% m/z--> : 20 30 40 50 60 70 80 90 100110120130140150160170180190 200 210 Abundance■ #7245: Butane, 2,3-dichloro-2-methyl- 77

V 5000- A== 7.40 1 1 TT’’ "T r7ii“| r r । > [ 7.60 7.80 8.00 27 m/ z 76.00 43.04% 53 63 89 105 A .... i I , I I I 1 i i I I I I I I I I I I I I I " 1 ''i" " iri 125 1111111111111111111111 > 111111111 ' i" " I i" " i"' m/z-> 20 30 40 50 60 70 80 90 100110120130140150160170180190 200 210 Abundance #14970: Acetic acid, chloro-, anhydride 77 I N................. I | r 1| . .............. i 115BI Ii I| I I | i i i

7,40 7.60 7.80 8.00 5000- m/z 42.95 40.98% 49

—35 L I I I I I 1 I I I I I I I t I I I I I I 1 r " ' r 1111 111111 r "' I'11" r " 11" " i11 121 149 I I I I I [ I I I I I I I I I I I I I I I I I I I I I I

m/z-> 20 30 40 50 60 70 80 90 100110120130140150160170180190 200 210 Abundance। #11248: Propane, 2-bromo-1 -chloro- — 77 7.40 7.60 7.80 8.00 41 m/z 69.00 32.36%

5000

27

m/z-> 61 < 11 < Nin । I’ 1111 I I I I I I I I I 1 I I I I I 20 30 40 50 60 70 80 90 100110120130140150160170180190 200 210 197 158 | i i i i [ i r i < | i I i i | ITTI । i i i i । I i i i । i i I I । i i i i | i il i । I' " ‘ I " ‘ A . „ w. , I I < I l . I ll ’ 7.40 T41 ’ " I • ' ' 1 I 7.60 7.80 8.00

8837.D GCMS0412.M Wed Apr 24 08:36:37 2002 Page 4

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