GCMS unknowns report for sample AE02561, March 2002

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Data File : C:\HPCHEM\l\DATA\MAR1902\2561.D Vial: 20 Acq On : 20 Mar 2002 11:43 pm Operator: Sample : gc/ms scan 3/4 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Library- : C:\DATABASE\NBS75K.L

Peak Number 1 1,3-Dioxolane, 2-(3-bromo-5,5, Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

8.15 0.54 ug/1 72815 1,4-Dichlorobenzene-d4 12.27

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,3-Dioxolane, 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 17 2 N-Ethylformamide 73 C3H7NO 000627-45-2 9 3 Silane, etramethyl- 88 C4H12Si 000075-76-3 9 4 Butane, /2 -methoxy-2-methyl - 102 C6H140 000994-05-8 9 Abundance » Scan 338 (8.146 min): 2561.D (-) m/ z 73.0.0 100.00% 73

5000 43 /

m/z-? -.......... + 10 20 30 40 50 60 , , ,55 87 ......... , । 1 1 ' i ■ T ’r TTEIBTTT ' i * ■ * 1 i ■ ■ ‘ 'i' 70 80 90 103 100 110 120 7.80 m/ z 8.00 43.05 8.20 8.40______ 29.37% Abundance #49423; 1,3-Dioxolane, 2-(3-bromo-5,5,5-lrichlora-2,2-dimet 73

5000 4 TII 7.80 8.00 8.20 8.40___ 45 m/ z 45.05 10.56% 36 55 67 109 115 TIT । । । *IBC—m/n1n/nm , । TT ______ 10 20 30 40 50 60 70 80 90 100 110 120 Abundance 30 73 A-- 1 । ■ ■ ■ ■ । ■ __ 7.80 8.00 8.20 8.40_____ 5000 m/ Z 41.05 10.50% 44 58

15 1 1 । 1 1 1 i ‘ ' 1 1 i 1 1 1 1 i 1 ‘ ' 1 i 1 1 Tit 1TEEI |-r-r-r-i-> 111/111.8 --nnr)n/d/1B.T m/z->.......... 10 20 30 40 50 60 70 80 90 100 110 120 Abundance AA #845: Silane, tetramethyl- 73 7.80 8.00 8.20 AA 8.40______ m/ z 71.0.0 6.16% A 5000

45

m/z-> 15 TTIBI 10 20 31 30 ...40 4—5055...... 60 70 88 TIIBn— 80 90 Bnnmm—B/aannmon 100 110 120 7.80 8.00 —A.. 6.20 8.40

2561.D GCMS0308.M Thu Mar 21 14:17:24 2002 Page 1

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