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GCMS quantitation results for sample AE03471, March 2002

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Quantitation report listing response data for deuterated internal standards and surrogates from a March 14, 2002 analysis.

NYC-WTC_000038458–000038464

Folder label: “GCMS X 2/26/02 A 2/28/02

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NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\022802\03471.D Vial: 20 ■ Acq On 1 Mar 2002 4:08 am Operator: McLean Sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 13 06:53:48 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\1\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.58 150 1132238 20.00 ug/L 0.00 10) Naphthalene-d8 13.05 136 2991026 20.00 ug/L 0.00 17) Acenaphthene-dl0 18.16 164 1682484 20.00 ug/L 0.00 29) Phenanthrene-diO 22.52 188 2591629 20.00 ug/L 0.00 38) Chrysene-dl2 30.33 240 2303177 20.00 ug/L -0.03 44) Perylene-dl2 34.20 264 1423111 20.00 ug/L -0.02

System Monitoring Compounds 37) 2,4-ddd surr 27.46 235 208183 5.06 ug/L 0.00 Spiked Amount 5.000 Recovery = 101.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.32 74 5540 0.16 ug/L 100 3) bis(2-chloroethyl) ether 0.00 93 0 N.D. 4) 1,3 - Dichlorobenze 0.00 146 0 N.D. 5) 1,4 - Dichlorobenzene 0.00 146 0 N.D. 6) 1,2 - Dichlorobenzene 0.00 146 0 N.D. 7) 2,2 ' - oxybis (l-Chloropr 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophrone 0.00 82 0 N.D. 13) bis(2Chloroethoxy) methan 0.00 93 0 N.D. 14) 1,2, 4Trichlorobenzene 0.00 180 0 N.D. 15) Naphtalene 0.00 128 0 N.D. 16) Hexaclorobutadiene 0.00 225 0 N.D. 18) HexacLorocyclopentadiene 0.00 237 0 N.D. 19) 2-chlonaphthalene 0.00 162 0 N.D. 20) Dimetlphthalate 0.00 163 0 N.D. 21) 2,6-D.itrotoluene 0.00 165 0 N.D. d 22) Acenathylene 0.00 152 0 N.D. 23) Acenathene 0.00 153 0 N.D. 24) 2,4-Ditrotoluene 0.00 165 0 N.D. 25) Diethhthalate 0.00 149 0 N.D. 26) 4-Chiophenyl -phenyl ethe 0.00 204 0 N.D. 27) Fluort 0.00 166 0 N.D. 28) Azobem/ 1,2 -Diphenylhyd 0.00 77 0 N.D. 30) N-Nitodiphenylamine 0.00 169 0 N.D. 31) 4-Bromenyl-phenyl ether 0.00 248 0 N.D. 32) Hexackobenzene 0.00 284 0 N.D. 33) phenanene 0.00 178 0 N.D. 34) Anthrae 0.00 178 0 N.D. 35) Di-n-blphthalate 24.67 149 5619 0.03 ug/L 79 36) Fluorane 0.00 202 0 N.D. 39) Pyrene 0.00 202 0 N.D. 40) Butylblphthalate 0.00 149 0 N.D. 41) Benzo antracene 0.00 228 0 N.D. d 42) Bis (2ylhexyl) phthala 30.94 149 131174 1.26 ug/L 96 43) Chrysei 0.00 228 0 N.D. d 45) Di-n-Oohthalate 0.00 149 0 N.D. 2 46) Benzo luoranthene 0.00 252 0 N.D. (#) = qualifut of range (m) = manual integration )3471.D 50&M Wed Mar 13 06:54:37 2002 Page 1

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