GCMS calibration table for TCLP method, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : M:\INSTRU~1\2O9\DATA\DEC13O1\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Carbamothioic acid, O-butyl es Concentration Rank 15

R.T. EstConc Area Relative to ISTD R.T.

16.52 1.78 ug/1 844994 Naphthalene-d8 15.28

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Carbamothioic id, O-butyl ester 133 C5H11NOS1 000692-99-9 10 2 Carbamothioic acid, O-isobutyl este 133 C5H11NOS1 082360-09-6 9 3 Propanedinitrile , methylene- 78 C4H2N2 000922-64-5 7 4 2-Butenedjnitrile , (E)-___________ 78 C4H2N2 000764-42-1 7 'Abundance Scan 1250 (16.517 min): 29522.D (-) m/z 77.95 100.00% : 78

5000- 41 56 133 _ 16.20 16.40 16.60 16.80 ■ i ' ’ ■ ■ i 35 | 14750—Lf2 ■ ■ ■ 1 I 1 71 1 ')'rl 90 100 108 ... 1 m/z 41.00 34.48% miz-> 20 30 40 60 70 80 90 100 110 120 130 140 Abundance #5928: Carbamothioic acid, O-butyl ester 78

41 5000- ■i 1 1 ' • । 16.20 16.40 16.60 16.80 . 56 133 m/z 43.95 31.11% 27

J | I ?2 ' I ' 1 1 ' I1 1 1 1 I ' TTT m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #5929: Carbamothioic acid. O-isobutyl ester 78

16.20 16.40 16.60 16.80 56 5000 m/ Z 55.9.5 22.28% 133 44 27 38 I- I ,62 86 • i ■ ■ ■ • i ■ * “ I ' ' r-p-r-r-r-j-n T-J-T • i • ■ l ■ l ■ ■ ‘ | • ' ■ ■ | ■ ■ • ■ | • • ■ • | T . . . | .

m/z-> 20 30 40 50 60 70 80 90 100 110 12C 130 140 'Abundance #62625: Propanedinitrile, methylene- 718 16.20 16.40 16.60 16.80 51 m/z " 21.53% 5000- 26 38

m/z—> T 20 —.1 —4 30 40 50 60 70 80 90 100 110 120 130 140 । - । < ■ <> । --------- 16.20 16.40 16.60 16.80

29522.D GCMS1126.M Tue Jan 08 10:53:56 2002 Page 3

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