GCMS analysis comments, sample AD29086, Dec 2001

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Library Search Compound Report $ Data File : C: \HPCHEM\ 1 \DATA\DEC1001\29086.D Vial: 35 Acq On : 11 Dec 2001 9:50 pm Operator: 209 GALOS Sample : gc/ms scan ll/30a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 N-Ethylformamide Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

7.60 3.43 ug/1 878893 1,4-Dichlorobenzene-d4 11.67

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 N-Ethylformamide 73 C3H7NO 000627-45-2 9 2 1,3-Dioxolane, 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 9 3 1-Butanamine, 3-methyl- 87 C5H13N 000107-85-7 7 4 1,3-Dioxolane, 2-methyl- 88 C4H802 000497-26-7 5 Abundance Scan 278 (7.600 min): 29086.D (-) m/z 73.0,0 100.00% 73

5000 43 -10— TBBm . . । . i 37, |,I,| 49 55 67, 1 87 103 7.20 7.40 7.60 7.80 8.00 37,1 Ir ' I 1 1 1 ‘ I ' * * ’ i 11 ■ I | l 1 » * | i m/z 43.05 26.40% 10 20 30 40 50 60 70 80 90 100_ 110 120 Abundance #292: N-Ethylformamide 30 73

5000 i j . . . . r r । i । । । । it i > । i i 44 58 7.20 7.40 7.60 7.80 8.00 m/z 41.0,0 10.15% 15 — — ■ • i 1 • i ■ • I ‘ 1 ' ‘ I ‘ 1 ‘ ‘ I ‘ ‘ ' I ' ‘ ‘ I ‘ ‘ ‘ ‘ ‘ I ‘ ‘ miz-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #49423: 1,3-Dioxolane. 2-(3-bromo-5,5 5-trichloro-2.2-dimet 73 “TTTTTPTTrTff 7.20 7.40 7.60 7.80 8.00 5000 m/z 44.9.5 9.79% 45 36 55 67 | TIDddnnn.mm IT TTI TTTn iri » j i r j j "j i .... 109,115, miz-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #763: 1-Butanarm ine, 3-methyl- "TT T IIm T 1 y pm-, Tgur 30 7.20 7.40 7.60 7.80 8.00 m/z 71.0,0 6.44% 5000

15 1 41 , 55 70 87 11 I 1 Th 1 I 11 TTIIf i । i j । TTT i • • ‘ * I > • 1 ■ i • 1 i ■ • ‘ ■ TTT > । । । i । > । । i TI I I TT1.s 1] I T T TTTTT T TT miz-> 10 20 30 40 50 60 70 80 90 100 110 120 7.20 7.40 7.60 7.80 8.00

29086.D GCMS1126.M Wed Dec 12 15:51:24 2001 Page 1

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