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GCMS analysis comments, sample AD28859, December 2001

Machine-extracted title · confidence 95%

Gas chromatography-mass spectrometry analysis results for sample AD28859 showing bis(2-Ethylhexyl)phthalate presence at 0.81 ug/L with quality control notes on LCS standard recover

NYC-WTC_000035505–000035513

Folder label: “GCMS X 11/27/01 A 12/7/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\DEC0 601\28859.D Vial: 31 Acq On 7 Dec 2001 4:57 am Operator: 209 GALOS Sample 11/27 gc/ms scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2,4-Diethyl-5-methylthiazole Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

28.81 0.99 ug/1 377544 Phenanthrene-dl0 24.98

Hit# of 5 Tentative ID MW MolForm CAS# ------------------------------------------------------- A

1 2,4-Diethyl-5-methylthiazole 155 C8H13NS 052414-89-8 35 V 2 1-Propanamine, 3-methoxy- 89 C4H11NO 005332-73-0 25 3 Benzene, 1-[(2/chloroethyl)sulfonyl 218 C9H11C1O2S 022381-53-9 12 4 Acetic acid, (4-methylphenyl)sulfo 242 C11H14O4S 002850-19-3 12 Abundance Scan 2588 (28.805 min): 28859.D (-) m/ z 91.0,0 100.00% 40 72 91 155

5000 - 59 199

miz-> 20 - 40 60 — 80 100 1104-114139 L, .166. + 120 140 160 180 173 IRA

200 216 299 244 । zzy 220 , 240 28.40 28.60 28.80 29.00 29.20 m/ z 72.00 81.83% Abundance #67210: 2,4-Diethyl-5-methylthiazole 140 1 55

59 100 __- 5000 - 28.40 28.60 28.80 29.00 29.20 45 m/ z 39.95 81.36% .. I ' ' ' ■ i ■ ' ■ • i ' ' ' 71 80 85 " -127 m/z-> 20 40 60 100 120 140 160 180 200 220 240 Abundance #882: 1-Propanamine, 3-methoxy- 30 Tma • i • • ■ ' । ■ 28.40 28.60 28.80 29.00 29.20 5000 । 72 m/z 154.9.5 70.45% i 45 56 I 1 i ■ ' 189........ ......................................... m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #27044: Benzene, 1-[(2-chloroetbyl)sulfonyi]-4-methyl- 91 155 28.40 28.60 28.80 29.00 29.20 ‘m/z 44.95 49.60% 5000 218

m/z-> 20 40 60 80 LX 100 120 A 139

140 *1- j ■ i ' 11 । 160 180 190 X200—..220 1...... 240 TTTr J V 1TTTTRRTPTT 28.40 28.60 28.80 29.00 29.20

28859.D GCMS1126.M Wed Dec 12 11:38:29 2001 Page 1

NYC-WTC_000035512

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