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GCMS unknowns analysis results for sample AD28334, Jan 2002

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis for unknown compounds and surrogate recovery in sample AD28334 conducted on January 9, 2002.

NYC-WTC_000033936–000033944

Folder label: “GCMS X 11/20/01 A 11/26/01

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NYC 9/11 Public Portal Document . Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\NOV2601\28334 .D Vial: 13 Acq On : 28 NOV 2001 5:00 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 1,4-Dichlorobenzene-d4 Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

11.56 0.51 ug/1 122042 1,4-Dichlorobenzene-d4 11.69

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1, 4-Dichlorobenzene-d4 150 C6C12D4 003855-82-1 64 f 2 Benzene-£2,3,4-d4-, 5, 6-dichloro- 150 C6C12D4 002199-69-1 32 3 Benzofuran, 7-chloro- 152 C8H5C10 024410-55-7 9 4 Acenaphthylene 152 C12H8 000208-96-8 9 Abundance Scan 710 (11.564 min): 28334.D (-) m/z 149.90 100.00% 1$0

5000 115

52 78 IIIIP 87 11.20 11.40 11.60 11.80 । miz-> । 11 r 30 38 ++.।.i.-H—r 3— 1 n —l TT.'. 1.p. TTIpur 11I‘T 40__ 50 60 70__ 80__90 100 110 120 130 140 150 T T 160 m/z 151.90 60.00% Abundance #9593: 1,4-Dichlorobenzene-d4 150

5000- 115 78 11.20 11.40 11.60 11.80 52 m/z 115.00 41.26% 35 87 | : 1 ' I ' ' 1 11 ' 11 11 111 11 1 r‘ TPTRTTTT miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9502: Benzer1,2,3,4-d4-, 5.6-dichlaro- 150

115 11.20 11.40 11.60 11.80 5000 52 78 m/z 78.00 22.07%

35 87 11'1111 ’ i1'1111 TTITrrnmr 1TITTPTTTTTT m/z->____ 30__ 40__ 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #10136: Benzofuran, 7-chloro- 152 11.20 11.40 11.60 11.80 m/z 52.00 . 17.70% 5000 89

63 35 49 ,|| /3 J 125 । 11 > ।' I • 1 ' > 11 > > ■ T’T ' ■ | TT i । 11 > ri । T TTTTTIUTTI 1 "gn > । । । । । P । TTT TT , TTT । । , । , m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 11.20 11.40 11.60 11.80

28334.D GCMS1126.M Thu Jan 03 12:49:40 2002 Page 1

NYC-WTC_000033943

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GCMS comments for sample AD28265, Nov 2001 · Box DEP Box 21

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Analytical commentary for sample AD28265 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

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GCMS comments for sample AD28149, Nov 2001 · Box DEP Box 21

NYC-WTC_000033780

Analytical commentary for sample AD28149 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

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