GCMS method parameters and calibration table, Dec 2001

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\DEC1801\LB.D Vial: 2 Acq On : 18 Dec 2001 4:49 pm 2222C , o Operator: GALOS Sample : gems unknown 11/16 276294 Inst : GC/MS Ins Mise : MS Integration Params: RTEINT.P 2)638, 01 22631 634 Multiplr: 1.00

Quant Time: Dec 19 9:53 2001 22628-671 Quant Results File: NP112701.RES Quant Method : c.\HPCHEM\I\METHONSZR4Y423?% 2£7Integkatot) Title : 208 625/TCLP calibration table Last Update : Wed Nov 28 15:33:44 2001 Response via : Initial Calibration DataAcq Meth : HP032901

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.87 152 862635 20.00 ng/uL -0.07 19) Naphthalene-d8 15.48 136 3388517 20.00 ng/uL -0.07 31) Acenaphthene-diO 20.76 164 1468237 20.00 ng/uL -0.07 49) Phenanthrene-diO 25.16 188 2102061 20.00 ng/uL -0.08 59) Chrysene-dl2 33.16 240 1329205 20.00 ng/uL -0.08 68) Perylene-dl2 37.24 264 956065 20.00 ng/uL -0.09

System Monitoring Compounds 4) 2 -Fluorophenol 0.00 112 0 0.00 ng/uL Spiked Amount 75.000 Range 18 42 Recovery = 0.00%# 5) Phenol-d5 0.00 99 0 0.00 ng/uL Spiked Amount 75.000 Range 19 32 Recovery = 0.00%# 6) 2-Chlorophenol-d4 11.87 132 664 0.01 ng/uL 0.45 Spiked Amount 75.000 Range 34 84 Recovery = 0.01%# 7) 1,2-Dichlorobenzene-d4 12.03 152 305 0.01 ng/uL -0.42 Spiked Amount 50.000 Range 26 73 Recovery = 0.02%# 20) Nitrobenzene-d5 0.00 82 0 0.00 ng/uL Spiked Amount 50.000 Range 55 98 Recovery = 0.00%# 32) 2-Fluorobiphenyl 18.89 172 144 9 0.02 ng/uL 0.06 Spiked Amount 50.000 Range 42 78 Recovery = 0.04%# 33) 2,4,6-Tribromophenol 0.00 330 0 0.00 ng/uL Spiked Amount 75.000 Range 45 96 Recovery = 0.00%# 62) Terphenyl-dl 4 0.00 244 0 0.00 ng/uL Spiked Amount 50.000 Range 58 98 Recovery = 0.00%#

Target Compounds Qvalue 2) Pyridine 0.00 79 0 N.D. 3) N-nitrosodimethylamine 0.00 74 0 N.D. 8) Phenol 0.00 94 0 N.D. 9) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 10) 2-Chlorophenol 0.00 128 0 N.D. 11) 1,3-Dichlorobenzene 0.00 146 0 N.D. 12) 1,4-Dichlorobenzene 0.00 146 0 N.D. 13) 1,2-Dichlorobenzene 0.00 146 0 N.D. 14) 2-Methylphenol 0.00 108 0 N.D. 15) 2,21 -oxybis(1-Chloropropan 0.00 45 0 N.D. 16) 3&4-Methylphenol 0.00 108 0 N.D.

(#) = qualifier out of range (m) = manual integration LB.D NP112701.M Wed Dec 19 09:53:59 2001 Page 1

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