GCMS scan report for Method 508, April 2002

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Data File : C:\MSDCHEM\1\DATA\020419\08430.D Vial: 17 Acq On : 19 Apr 2002 11:53 pm Operator: Nefliu Sample : sample Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 12 Tris(trifluoromethyl)borane... Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T. 42.16 0.25 ug/1 432975 Perylene-dl2 43.16

Hit# of 2 Tentative ID MW MolForm CAS# Qual

1 Tris(trifluoromethyl)borane glycine 293 C5H5BF9NO2 1000162-80-8 1 2 9-But-3-enyl-17-hydroxy-10-oxa-l... 382 C20H30O3S2 1000192-36-0 1

Abundance Scan 6651 (42.157 min): 08430.D (-6613) (-) m/ z 40.10 100.00% "A-AWwNWWWWVw 40 8000

6000

4000 41.80 42.00 42.20 42.40 m/ Z 276.20 19.11% 2000 276 207

m/z-> O-pr 86 Ti 57mll 11!'1 "I "Tl I ” " I " "I " " 11 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 A........... Abundance #874: Tris(trifluoromethyl)borane glycine 30 ............. ,......... , 41.80 42.00 42.20 42.40 8000 m/z 275.20 12.20%

6000

4000

2000 78 41 80 42.00 42.20 42.40 58 104134 154 174 274 m/z 49.00 9.77% 0V -H - — 204 224 l-rl" " 11" ' I " " I" ,J| i" " i' ■" I" " I" " I" " I"' rn/z—> Abundance 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 23 #328:9-But-3-enyl-1 7-hydroxy-10-oxa-1,5-dithia-spiro[5.1 3... MMWMyyWMbyhhl 8000

6000 41.80 42.00 42.20 42.40 m/z 277.20 9.60% 4000

2000 59 275

/z—> ovTpT .76.110,161, 175203 233 307 "i■■ ■■ i"।।।■ |i। 382 11111p11'l""I'1" 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 ii ' 1 1 1 1 1 1 1 1 i ' ' ' ‘ i ' ■ ' 1 i ■ 41.80 42.00 42.20 42.40

08430.D SCAN020418.M Mon Apr 29 08:29:51 2002 Page 27

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