GCMS calibration data for TCLP method, May 2002

NYC 9/11 Public Portal Document quantitatlon Report (Q’l Reviewed)

Data File C:\HPCHEM\l\DATA\MAY0302\9572.D Vial: 46 Acq On 5 May 2002 12:06 pm Operator : Sample GC/MS SCAN 4/23 FB Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 7 14:53 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 12.19 152 501062 40.00 ug/1 -0.02 10) Naphthalene-d8 15.83 136 1833525 40.00 ug/1 -0.02 17) Acenaphthene-diO 21.14 164 982074 40.00 ug/1 -0.01 30) Phenanthrene-diO 25.57 188 1365688 40.00 ug/1 -0.02 38) Chrysene-dl2 33.64 240 893250 40.00 ug/1 -0.03 44) Perylene-dl2 37.87 264 590097 40.00 ug/1 -0.01

System Monitoring Compounds 28) TCMX 23.27 209 17768 3.72 ug/L -0.02 Spiked Amount 10.000 Recovery = 37.20% Target Compounds Qvalue 2) N-nitroso-dimethyl amine 0.00 74 0 N.D. 3) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,2'-oxybis(1-Chloropropan 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 14.53 82 3333 N.D. 13) bis(2-Chloroethoxy)methane 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 0.00 128 0 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. d 22) Acenaphthylene 0.00 152 0 N.D. 2 3) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 22.61 149 1941 N.D. 26) 4-Chlorophenyl-phenylether 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 29) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D. 31) N-Nitrosodiphenylamine 0.00 168 0 N.D. 32) 4-Bromophenyl-phenylether 0.00 248 0 N.D. 3 3) Hexachiorobenzene 0.00 284 0 N.D. 34) Phenanthrene 25.58 178 320 N.D. (#) = qualifier out of range (m) = manual integration 9572.D GCMS0501.M Tue May 07 14:53:38 2002 Page 1

NYC-WTC_000023099