GCMS calibration data for TCLP method, May 2002

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Data File C:\HPCHEM\l\DATA\MAY0302\9332.D Vial: 34 Acq On 5 May 2002 12:22 am Operator: Sample RE-EXT. Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.16 15.01 ug/1 977654 1,4-Dichlorobenzene-d4 12.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pent .one, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 CH2=C !H2C(O)OCH3 100 C5H802 003724-55-8 9 3 Acet ne 58 C3H60 000067-64-1 7 4 5-Hi en-2-one 98 C6H10O 000109-49-9 7 Abundance Scan 340 (8.158 min): 9332.D (-) m/z 43.05 100.00%| 43

5000 59 ............................... ............. , 1 1 i 1 1 1 ■ । ■ 1 1 । 1 1 ■ ' । 1 1 1 < । * 101 7.80 8.00 8.20 8.40 8.60 ............................... ■ ■ i ■ ■ ■ ■ j - ■ ■ - i ■ . ‘ . 53 . 69 ...... 83 ....... , I......... 11 1 i''-'11 I 1 ' ' ' i ' ‘ ' i ' 1 ' ■ i ' ' ' 1 1 1 ' 1 ' i ' । ■ m/z 59.10 42.83% mlz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7.80 8.00 8.20 8.40 8.60 m/z 58.10 16.14% 27 101

m/z-> ----- 10 20 30 40 50 +49 +83 I ■ ■ ■ ■ i ' ' 1 1 i ''' ■ ' i 1 60 70 80 90 +1, ) 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.35%

11111138 / 58 72 100 m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #94: Acetone 43 780 8.00 8.20 8.40 8.60 m/z 41.05 7.25% 5000 15 58 27 n) ''I1' ' i ■ 1l,1) ■ ' ' rl 1 i ' * 11/1/11 1+/**/11 1 ‘ 1 ‘‘ |+II —1 1 — । i । i i । । m/z—> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9332.D GCMS0501.M Tue May 07 12:01:47 2002 Page 1

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