Volatile organic compounds analysis results, March 21, 2002

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Data File : C:\HPCHEM\1\DATA\02mar21\6584F.D Vial: 18 Acq On : 22 Mar 2002 5:19 am Operator: 201-wb Sample : nyc; fb Inst : GC/MS Ins Mise : March 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\HP031802.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Library : C:\DATABASE\NBS75K.L Peak Number 1 Ethanamine, N-methyl-N-nitroso Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 15.77 0.03 ug/L 16059 1,4-DIFLUOROBENZENE 15.10 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Ethanamine, N-methyl-N-nitroso- 88 C3H8N20 010595-95-6 3 2 Sulfide, allyl methyl 88 C4H8S 010152-76-8 3 3 1,2-Hydrazinedicarboxaldehyde 88 C2H4N2021 000628-36-4 3 4 Propanoic acid, 2-methyl- 88 C4H802 ______ 000079-31-2 3 Abundance Scan 692 (15.766 min): 6584F.D (-) m/z 114.05 100.00% 1 4

5000 63 88 15.40 15.60 15.80 16.00 _______________ 44________________ m/z 62.95 27.73% ■ i ■ ■ ‘ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■11 ■ ■ ■ ■ i ■ ■ ■ ■ i111' 111 i ■'1 ■ i ‘' ■ ■ I ■ rn/z--> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #62895: Ethanamine, N-methyl-N-nitroso- 42 88

5000 15.40 15.60 15.80 16.00 m/z 88.00 25.90% 56

/z-> ■ i ‘ ■ ■11' ■ ■ ■ i ■ ■ ■' i 10 20 30 Mlmm 40 50 60 70 80 90 rl' ‘ ‘ ‘ I' '' ‘ I' ‘' I ‘ ‘ 100 110 120 Abundance #62927: Sulfide, allyl methyl 411

73 88 15.40 15.60 15.80 16.00 5000 m/z 43.95 6.97%

61 MWWVu"Wy m/z-> 10 'I'''‘ I ‘■ I' ■' 'I' 20 444 30 40 50 60 70 80 90 100 110 120 *mmmmmm Abundance #62891: 1,2-Hydrazinedicarboxaldehyde 31 15.40 15.60 15.80 16.00

5000 60 88

45 Luig,,-... i ■ ■ ■ ■ i ■ ■ ■ ■ i '1 ■ ■ i ■1 m/z--> 10 20 30 40 50 60 70 80 90 100 110 120

6584F.D HP031802.M Fri Mar 22 05:58:46 2002 Page 1

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