Volatile organic compounds blank results, Feb 28 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02feb27\0227R5.D Vial: 2 Acq On : 27 Feb 2002 6:06 pm Operator: 201-wb Sample : ref Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 27 18:44 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Wed Feb 27 17:11:09 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.17 114 2906142 5.00 ug/L 0.00 24) CHLOROBENZENE-D5 21.83 117 2944327 5.00 ug/L 0.00 52) 1,4-DICHLOROBENZENE-D4 27.00 152 1527671 5.00 ug/L 0.00 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.41 65 927776 4.94 ug/L 0.00 Spiked Amount 5.000 Recovery = 98.80% 3) 4-BROMOFLUOROBENZENE 24.42 174 1173175 4.99 ug/L 0.00 Spiked Amount 5.000 Recovery = 99.80% 25) TOLUENE-D8 18.53 98 3573858 5.03 ug/L 0.00 Spiked Amount 5.000 Recovery = 100.60% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.90 85 770965 9.58 ug/L 99 5) CHLOROMETHANE 5.52 50 681207 7.94 ug/L 99 6) VINYL CHLORIDE 5.65 62 449274 8.08 ug/L 96 7) BROMOMETHANE 6.63 94 428408 7.98 ug/L 92 8) CHLOROETHANE 6.78 64 391909 8.23 ug/L 95 9) TRICHLOROFLUOROMETHANE 7.33 101 738126 6.93 ug/L 95 10) Isopropyl Alcohol 7.94 45 14400 5758.38 ug/L 56 12) ACETONE 8.31 43 125345 8.43 ug/L 98 13) 1,1-DICHLOROETHENE 8.67 61 748529 5.91 ug/L . 98 14) METHYLENE CHLORIDE 9.67 49 1285003 7.92 ug/L 97 15) METHYL TERT BUTYL ETHER 9.98 73 1074659 6.29 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.34 61 1068198 6.23 ug/L 100 17) 1,1-DICHLOROETHANE 11.24 63 1397356 6.59 ug/L 99 18) 2-BUTANONE (MEK) 12.07 43 217471 6.83 ug/L 97 19) 2,2-DICHLOROPROPANE 12.45 77 1036505 6.63 ug/L 100 20) CIS-1,2-DICHLOROETHENE 12.55 96 934738 7.17 ug/L 99 21) CHLOROFORM 12.89 83 1548333 6.96 ug/L 100 22) BROMOCHLOROMETHANE 13.26 49 761995 6.95 ug/L 100 23) 1,2-DICHLOROETHANE 14.61 62 982860 6.99 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.78 97 1078374 6.85 ug/L 100 27) 1,1-DICHLOROPROPENE 14.10 75 1147413 7.44 ug/L 98 28) CARBON TETRACHLORIDE 14.35 117 913906 6.92 ug/L 100 29) BENZENE 14.69 78 3214255 7.36 ug/L 100 30) TRICHLOROETHENE 15.97 95 979891 7.63 ug/L 98 31) 1,2-DICHLOROPROPANE 16.33 63 967225 7.63 ug/L 98 32) DIBROMOMETHANE 17.01 174 484245 7.28 ug/L 97 33) BROMODICHLOROMETHANE 16.86 83 1161902 7.31 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.33 63 288222 7.17 ug/L 99 35) METHYL ISO-BUTYL KETONE 17.42 58 164951 7.30 ug/L 87 36) CIS-1,3-DICHLOROPROPENE 17.95 75 1317420 7.62 ug/L 100 37) TOLUENE 18.70 91 3778910 7.87 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.97 75 1003328 8.11 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.36 97 632260 7.67 ug/L 98 40) TETRACHLOROETHENE 20.14 166 1072633 7.78 ug/L 98 41) 1,3-DICHLOROPROPANE 19.89 76 1133051 7.50 ug/L 98 42) DIBROMOCHLOROMETHANE 20.59 129 733565 7.41 ug/L 99 43) 1,2-DIBROMOETHANE 21.03 107 632069 7.53 ug/L 96 44) CHLOROBENZENE 21.91 112 2600308 7.91 ug/L 100 45) 1,1,1,2-TETRACHLOROETHANE 21.96 131 852541 7.81 ug/L 99 46) 2-HEXANONE 19.26 43 611088 10.63 ug/L 91 47) ETHYLBENZENE 21.95 91 4548667 8.35 ug/L 99 (#) = qualifier out of range (m) = manual integration 0227R5.D HP022702.M Wed Feb 27 18:44:32 2002 Page 1

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