GCMS calibration data AE11284, DEP Labs, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\HPCHEM\1\DATA\MAY3002\12095.D Vial: 14 Acq On : 31 May 2002 2:51 am Operator: Morgan Sample : re-ext Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) *ee Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.06 0.92 ug/1 70719 1,4-Dichlorobenzene-d4 12.06 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 78 2 2-Hexanol, 2-methyl- 116 C7H160 000625-23-0 25 3 Morpholine, 4-methyl- 101 C5H11NO 000109-02-4 9 4 Acetone 58 C3H60 000067-64-1 9 Abundance Scan 329 (8,062 min): 12095.D (-) m/z 42.90 100.00%| 40

59 5000

mz-> Abundance ’’I’ 10 —.. r, +5+ 20 30 40 50 1m 60 70 80 83

#64275:2-Pentanone, 4-hydroxy-4-methyl- -+ 90 101

100 110 03111*1*f****1* 1 Mp-TT

m/z 7.80 8.00 59.00 8.20 8.40 50.52%

40

5000 PIP TI ■ ' ■ 59 7.80I 8.00 8.20 8.40 m/z !58.00 19.75% 15 31 . 101 , , r, I, 83 |

. ..I ■ ■ i ' 1 ■ ■ i ■ ■ 111 ■ ■ ■ i ■ 1*1’1 1 i 1 ■ • ■ i 1 ■ • ■ i ■' ■ ■ ■ i 1 1 1 1 r' 1 1 1 i 1 miz—> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64355:2-Hexanol, 2-methyl- 59 7.80 8.00 8.20 8.40 5000 m/z 101.05 17.24%

31 45 101

n/z-> Abundance L• ■ _ , 1 1 . ....... 531,• | .... i ■ ■ ■ ■ i • ■ • ■ i ■ ■ ■ ■ i • ' ' ■ i • ■ 1 — 10 20 30 40 50 60 ........83........... 69 ■ ■ 1 ■ | 1 1 ' 1 i 1 ' ’ 70 #1640: Morpholine, 4-methyl- 80 90 ....... I+’1*’I+I 100 110 । V__ j •1 ■ ■ । ■1 ■ ■ ।‘ ■ ।1 • • • । ■ ■1 ' 40 7.80 8.00 8.20 8.40 | m/z 41.0.0 7.01%

5000

15 101 27 71 56 TTnn TI n/z—> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40

12095.D GCMS0520.M Fri May 31 11:34:38 2002 Page 1

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