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GCMS analysis results, sample AE12288, June 2002

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Gas chromatography mass spectrometry results for sample AE12288 including surrogate recovery data analyzed on June 7, 2002.

NYC-WTC_000014189–000014213

Folder label: “GCMS X 5/24/02 A 5/29/02

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NYC 9/11 Public Portal Document Library searen compound Report; Data File : C:\MSDCHEM\l\DATA\052902\12288.D Vial: 7 Acq On : 29 May 2002 2:58 pm Operator: McLean Sample : gc/ms scan 5/24 fb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSClNT.e

Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 5 Propiolonitrile Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 3.86 0.81 ug/L 580596 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual l Propiolonitrile 51 C3HN 001070-71-95 2 Imidazol, 4-fluoro- 86 C3H3FN2 030086-17-02 3 Ethane, 1,1-difluoro- 66 C2H4F2 000075-37-6 2 4 Ethane, 1,1-difluoro- 66 C2H4F2 000075-37-6 2 Abundance Scan 133 (3.861 min): 12288.D (-132) (-) m/z 51/10 100.00% 36 51 /. 86

5000 44 47 JU mpmmpm 83 m/z 3.60 3.80 35 _ 10 4.00 4.20 _______ 94.12%

."ran 0- miz-> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12371: Propiolonitrile 5h1 M 5000 "r 1 1 1 1 1 1 1 1 i ■ • • ' i ' ■ 3.60 3.80 4.00 4.20 m/z 86.00 67.65%

miz-> 0- 1}’ 0 12,18,.77.1.,32.,34/..,47. 5 10 15 20253035404550556065 70 75 80859095 *]]

Abundance #34862: Imidazol, 4-fluoro- 85

3.60 3.80 4.00 4.20 5000 m/z 44.05 39.37%

59 0- TpppptpTgE '"in..,. m/z-> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111062: Ethane, 1,1-difluoro- 51 3.60 3.80 4.00 4.20 m/z 86.90 35.29% 5000 65 47 15 27 24

n/z-> 0 -2././124,19.24/.324....43. +4 0 *OmT[ 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20

12288.D 052202.M Mon Jun 03 09:37:03 2002 Page 8

NYC-WTC_000014201

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NYC-WTC_000014201Source: NYC Law Department, mirrored locally

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