GCMS analysis results for sample AE12475, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052802\12475.D Vial: 13 Acq On : 29 May 2002 12:04 am Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e 2 Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 2 Pyridine-d5- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 3.74 3.57 ug/L 2309330 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyridine-d5- 84 C5D5N 007291-22-7 9 2 Pent-4-enylamine 85 C5H11N 022537-07-1 4 3 Propiolonitrile 51 C3HN 001070-71-9 3 4 Perdeuterobenzene 84 C6D6 001076-43-3 2 Abundance Scan 113 (3.743 min): 12475.D (-112) (-) m/z 47.05 100.00% 47 51 /* 84

5000 88 ■ ' i ■ ' ' ■ i ■ ■ ■ ' i ■ ■ 1 ■ i ‘ ‘ i ‘ 40 3.40 3.60 3.80 4.00 Of TTpT-rrp-rTTp-rTTTTTT-rpr^^ 1 43 m/z 51.10 89.68% TH I “"I’ ’k‘ I ’* ’'! ’' “ I ‘‘1 ‘I 1 11 *' I miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance *33686: Pyridine-d5- 84

5000 52 ■ ■ i ■ ‘ ■ i ■ ■ • ■ i ' ■ i ‘ ■ i ■ 28 3.40 3.60 3.80 4.00 42 m/z 84.00 77.06% , 38

niz-> 14 24 01 mnudttnmnjmnntu—unt T 32.44+4484 , 62 66 76 | msapasgnangimnaba 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ■I' " ‘I “

Abundance #745: Pent-4-enylamine 30 ' ' i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i * ■ ' ■ i ' 3.40 3.60 3.80 4.00 m/z 50.10 46.79%

w"as 5000

43 re 39 , R7 27 Of " i >1 * • j > >1 • i >»< 11 *1 * • ।«11J H I.II 146 5053 | 63 70 84 niz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12371: Propiolonitrile 51 3.40 3.60 3,80 4.00 '' ‘ ‘ m/z 52.00 37.61% 5000i

iz-> 0i 5+12,+18,428,32.38,447. — 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.40 3.60 3.80 4.00

12475.D 052202.M Thu May 30 10:43:25 2002 Page 5

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