GCMS calibration table for TCLP extraction method

NYC 9/11 Public Portal Document Library searcn compound Keport

Data File : C:\MSDCHEM\l\DATA\052802\12287.D vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 13 N-(2-Acetylcyclopentylidene... Concentration Rank 15 R.T. EstConc Area Relative to ISTD R.T. 5.36 0.36 ug/L 241799 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual l N-(2-Acetylcyclopentylidene)cycl... 207 C13H21NO 1000100-48-5 4 2 N-Cyano-N' ,N’ ,N" ,N’’-tetramethy. . . 207 C8H13N7 074150-88-2 4 3 6-Methyl-5-[1-piperidinyl]-2,4-p... 207 C10H17N5 1000212-53- 4 4 2-Bthylacridine 207 C15H13N 1000147-64-9 4 Abundance Scan 388 (5.359 min): 12287.D (-382) (-) m/z 207.00 100.00%! 207

5000

48 133 36 500 5.20 5.40 5.60 5.80

niz-> 0- —l ■• >i • ■ i ■ ■ •11 ■ ■ ■ ■ i ■' ■ ■ i' ■' ■ i ■ ■ ■ ■ i “ " i ■' ‘11 ‘ 30 40 50 60 70 80 90 100110120130140150160170180190 200210 ■ ■ i • ■ • ■ i ■ ■' 1’13 m/z 207.90 35.09% Abundance #84801: N-(2-Acetylcyclopentylidene)cyctohexy)amine 207

124 164 41 5000 55 150 500 5.20 5.40 5.60 5.80 67 82 97 110 m/z 48.05 21.23% 192 178 136 ।

/z-> 0 HH 30 40 50 60 70 80 90 100110120130140150160170180190 200210 - "•i• '“i" i“ “

Abundance #84777: N-Cyano-N',N',N”,N“-tetramethyl-1,3,5-triazinetr... 207

135 5 00 5.20 5.40 5.60 5.80 5000 m/z 87.90 19.50% 192 44 178 164 71 82 96 ti/z-> 0 771911713 ............ ,I m— “ i" • ■ i ■ “ 'i ■ i 123 > l1" ■ i' ■ “ i“"i ■ ■1 ■ i ” 30 40 50 60 70 80 90 100110120130140150160170180190200210 I...... 12.14 ’ I’’* i" "i “ ■ i ‘ ■11 ‘

Abundance #84786:6-Methyl-5-[1-piperidinyl]-2,4-pyrimidinediamine 207 5.00 5.20 5.40 5.60 5.80 m/z 132.90 18.22%| 150 5000- 43 124 138 55 69 81 96 108 O-r । ■ Pl I । ill, ! ■ lll 111 h 111 rt’jrr- TT H- n rl165 n I') i >189 ’i 11. 178 i i’r 11111 rl"| ini mfz~> 30 40 50 60 70 80 90 100110120130140 150160170 180 190 200 210 5.00 5.20 5.40 5.60 5.80

12287.D 052202.M Thu May 30 10:40:29 2002 Page 16

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