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← Document results/DEP Box 15/GCMS X 5/24/02 A 5/28/02
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GCMS calibration table for TCLP extraction method

Machine-extracted title · confidence 90%

GCMS analysis results for sample AE11603 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000013968–000013996

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Llorary searcn compound keport

Data File : C:\MSDCHEM\l\DATA\052802\11603.D Vial: 9 Acq On : 28 May 2002 8:49 pm Operator: McLean Sample : 5/24 ad re-ext Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************** * * ********************************* Peak Number 12 1,2,3-Butatriene, 1-chloro- Concentration Rank 20 R.T. EstConc Area Relative to ISTD R.T. 4.89 0.22 ug/L 156662 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID' MW MolForm CAS# Qual 1 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 45 2 1-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7 38 3 Azetidine, 1-nitroso- 86 C3H6N20 015216-10-1/10 4 Acetaldehyde, ethylhydrazone 86 C4H10N2 020487-02-9 7 Abundance Scan 309 (4.895 min): 11603.D (-307) (-) m/z 71.00 100.00% 71 42 51 58 86 5000 36 4.60 4.80 5.00 5.20 nz-> 15 Op mll i ■ " ■ i 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 1′14* • i * “ • i ■ ‘1 ■ i ■ ■ i “ “ i “ “ i T-p-r-rq-rr m/z 51.10 82.30% Abundance #12404:1,2,3-Butatriene, 1-chloro- 51 86

5000 4.60 4.80 5.00 5.20 m/z 42.10 79.90% 60 39 Of TTIWpn* —Tp ‘ i ■ “ ■ i ‘ ■1 ■ i ■ “ ■ i ■"11 —aum 1 [ ■11 niz-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12406: 1-Buten-3-yne, 1-chloro-, (Z)- 51 86 ' ‘ ' i • ■ ■ ■ i ■ ■ • < I ■ ■ ■ ‘ i ■ • • ■ 4.60 4.80 5.00 5.20 5000 m/z 86.00 59.81%

miz-> 26 30 37 43 48 60 63 71 74 83. 0- I. | ■ 11 H I ■ ■ 7|~ III | H i ■■ ] 1111! 111111 — ■ “ I •11 • i •1 ■ • i • • " i1 “ 11 “ 11 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 +8990—— 95 Abundance #734: Azetidine, 1-nitroso- 3) 4.60 4.80 5.00 5.20 m/z 58.05 57.42% 41 50001 86 44 55 1 52 । 69 Oh ■ ■ i “ " i “ I 36 +H +—++ IM 11 rr j 11 f I [ 1111111 ri 111111 Hegus "i" m/z—> 15 20 25 3035404550556065 70 75 80 85 90 95 4.60 4.80 5.00 5.20

11603.D 052202.M Thu May 30 10:38:54 2002 Page 15

NYC-WTC_000013987

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NYC-WTC_000013987Source: NYC Law Department, mirrored locally

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