GCMS analysis results for sample AE12092, June 2002

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Library Search Compound Report

Data File : C: \MSDCHEM\ 1 \DATA\05230212092.D Vial: 13 Acq On : 23 May 2002 7:45 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 3-Amino-s-triazole Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

3.83 2.07 ug/L 1296640 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-Amino-s-triazole 84 C2H4N4 000061-82-75 4 2 3-Amino-s-triazole 84 C2H4N4 000061-82-5 4 3 Piperidine 85 C5H11N 000110-89-4 4 4 Dicyandiamide 84 C2H4N4 000461-58-5 2 Abundance Scan 127 (3.825 min): 12092.D (-126) (-) m/z 84.00 100.00% 84

49 5000 42 36 3.40 3.60 3.80 4.00 4.20 0 ■i “ " i■'■•i•■ ■ ■ i ■1 ■ ‘ i " I ■' i T1t ■ ■ i1 ■' ■ i'1' ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ‘ • • i “ ■■i■■1111 m/ z 49.10 61.64% nz-> 5 10 15 20253035404550556065 70 7580859095 Abundance #116542:3-Amino-s-triazole 84 28 57 5000 3.40 3.60 3.80 4.00 4.20 43 m/z 42.00 42.04% 54 —4314Ql. -+ **9m1"—67 _______ . w Ol IIIIISI—GBIA—5TTTT —0101000011117 “ i" ■ ■ i ■ miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #116543: 3-Amino-s-triazole 28 84

57 3.40 3.60 3.80 4.00 4.20 5000 m/z 44.00 34.84% 43

m/z-> 5 o qTTT 24 3134.,39+ 47 5154 ■ t ■■ ■■ I ■ ■11H 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 60 6568 7376 80 ‘ I' ■ ■ ‘ I ‘ UnVh/puM Abundance #116600: Piperidine *1dn/hm/ rr r-f > । 84 3.40 3.60 3.80 4.00 4.20 m/ z 84.95 29.65%

5000 56 28 44 41 15 or 70 31 3538, 5053 67 1 80 0 1111117110111/29 Th t HtHt R7 /z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.40 3.60 3.80 4.00 4.20

12092.D 052202.M Wed May 29 09:52:17 2002 Page 6

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