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GCMS analysis results for unknown compounds, sample AE10204, May 2002

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Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE10204 on May 10, 2002.

NYC-WTC_000044994–000045009

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050802\10204.D Vial : 22 Acq On 9 May 2002 8:31 am Operator: Mclean Sample 4/30 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 2 3-Amino-s-triazole Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T. 5.07 0.21 ug/L 161650 1,4-Dichlorobenzene-d4 9.93

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Amino-s-triazole 84 C2H4N4 000061-82-5 9 2 2,3,4,5-Tetrahydropyridazine 84 C4H8N2 000694-06-48 3 3-Amino-s-triazole 84 C2H4N4 000061-82-5 9 4 Aziridine, 2-methyl-3-(1-methyle. . . 99 C6H13N 010027-95-9 9 Abundance Scan 339 (5.071 min): 10204.D (-338) (-) m/z 84.00 100.00% 84 "MhMMwAwAHAAM 5000 44 35 53 127 r ' ' ' I 1 1 1 ' I ' 1 1 ' I 1 1 1 1 1 1 ' 1 1 4.80 5.00 5.20 5.40 01 1 1 1 1 ' 1 1 1 1 ' 1 I 1 , 1 i 1 11 1 i 1 1 1 ' i 1 ..... 98.............. 1 , ■ ' । 1 > 1 । । 1 r 1 ' । 1 । 1 1 । 1 । 1 1 । ' m/z 44.00 41.11% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 Abundance

28 #116542: 3-Amino-s-triazole 84 hyoason 57 5000 i-1 । । । । । rm । i । । । । i_ । । i [ i i T 4.80 5.00 5.20 5.40 43 m/z 39.00 33.16%

m/z-> 0 ' 1 i ' 20 H30 40 । । । 1 1 50 I । ii । i 60 67 70 l n । । । 80 I1 I kill I I I I I I I I I I I I I I I i I I 90 100 110 120 ______ I F

130 Abundance #33489: 2,3,4,5-Tetrahydropyridazine 28 84 ' i 11 ' 1 1 1 ' 1 1 ■ ■ 1 1 4.80 5.00 5.20 5.40 5000 55 m/ z 41.10 31.43% 41 69

Of 1 1 i 1 ' i TT i । ■ । । n i-! T ' 1 i 1 1 ' ' 1 1 1 1 1 i 1 ' 1 1 i 1 rr "14 n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #116543: 3-Amino-s-triazole i-1 । । । i । । i [ i m 11 । । । I y ’ । । 28 84 4.80 5.00 5.20 5.40 m/z 35. 10 30.74% 57 5000 43 A

/z-> 0 TIHHr 20 30 434—440 —51 50 T 60 68 74 i i rm [ m i i 70 80 l J 1 1 i 1 1 1 ■ I 1 ■ 1 ' i 1 1 1 1 i ' 1 1 1 i 1 90 100 110 120 130 1111LLIIM 4.80 5.00 5.20 5.40

10204.D 050102.M Thu May 09 13:38:28 2002 Page 5

NYC-WTC_000045003

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