GCMS calibration data for sample AE11931, May 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\052302\11931.D Vial: 11 Acq On : 23 May 2002 6:07 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 Thiophene Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

4.10 1.34 ug/L 810784 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Thiophene 84 C4H4S 000110-02-1 8 2 Thiophene 84 C4H4S 000110-02-19 3 Thiophene 84 C4H4S 000110-02-1 9 4 Krypton 84 Kr 007439-90-9 5 Abundance Scan 174 (4.102 min): 11931 .D (-172) (-) m/z 84.00 100.00% 49 84

58 5000 39 43 ■ 1 ■ i ■ ■ ' 1 i' । ■ ■ • ■ । ■ i 35 3.80 4.00 4.20 4.40 11! > 111 ri 111111111 ■ 1111 > 11111 j-n i > 111 > i 4m 0- "I" T ■n-rpn-rrp^TTpTTV^ m/z 49.10 94.74% m/z-> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33732: Thiophene 84

58 45 5000 ■ ■ ■ i ■ ■ ■ ■ i ‘ 1 ■ ■ i • ■ ■ ■ f ■ ■ 1 1 I

3.80 4.00 4.20 4.40 39 m/z 47.10 67.11% 50 । 0- 1 mhTTH++ tilhngt 12 26 32 । +4f.++.8Q,114,88,—44 miz—> 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #116585: Thiophene 84

58 3.80 4.00 4.20 4.40 ' ' 5000 m/z 58.10 62.72% 45 39 50 . 69 miz-> 0- o 12 18 26 32 „ , TTTTWTTTTTTTTTT 11 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Htmmm -7.99 Abundance #116584: Thiophene ■ ■ 1 i 1 ■ ■ ■ i ■ • ■ ■ i ■ ■ • ■ i ■ ■ ■ • i 84 3.80 4.00 4.20 4.40 58 m/z 51.10 55.70% 45 / 5000 39 50 26 32 11 69 0 o 1111111 n । r 1““!" tmlmalm y-r-p-n > » । । । i > । » i । » । « । । m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.80 4.00 4.20 4.40

11931.D 052202.M Wed May 29 09:50:56 2002 Page 10

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