GCMS analysis report sample AE09519, May 23, 2002

NYC 9/11 Public Portal Document ulbrary searcn compound Keporc.

Data File : C:\MSDCHEM\1\DATA\052102\9519.D Vial:. 14 Acq On : 21 May 2002 11:55 pm Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 2 l-Buten-3-yne, 2-chloro- Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T. 4.03 4.54 ug/L 2709670 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

l l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6 43 2 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 43 3 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3/38 4 l-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-9178 32 Abundance Scan 162 (4.031 min): 9519. D (-160) (-) m/z 49.10 100.00% 49 86

5000 39 3.60 3.80 4.00 4.20 4.40 0- p — I ‘ ‘ ‘' 11 ‘ ' I ' ‘ ‘ • I 1 ‘ 1 ‘ 1 1 1 ‘ ' I ‘ ‘ I ‘ ‘ *11’11111 m/z 51.10 76.27% m/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34744: 1-Buten-3-yne, 2-chloro- 51 85

5000 3.60 3.80 4.00 4.20 4.40 m/z 86.00 75.72% 60 0- ■ i1 ■1 • i ■ ■ ■ ‘ i ■ • ■11''' 1 ■ 11.111 ]. i. 11 <. i < j ■ ।1111 ruvre 111 ] ■ miz-> 30 35 40 45 50 55 60 65 70 . 75 80 85 90 95 Abundance #12405:4-Chlorobuten-3-yne 51 86 **I****I*’*-1** 3.60 3.80 4.00 4.20 4.40 5000 m/z 84.00 49.28%

60 59 0- l..■■■■■I.I, ' i1 ■ ■ ■ i ‘ ■ i ■1 ■ ■ i ■ • HTTp niz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12404: 1,2,3-Butatriene, 1-chloro- l ‘ ■ i • ■ ■ ■ i ■ 1 1 1 i • ‘ ‘ i • ■ ■ 51 86 3.60 3.80 4.00 4.20 4.40 m/z 47.10 31.34% 5000

59 0 119991 .J < • i > * > •60 | •1 • ■ i * • ■1 r1 *1 > i ‘11! ■ * *11 PTPTTT i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ' • ■ i ■ ■ ■ ■ i ■ ■ n/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20 4.40

9519.D 052202.M Wed May 22 11:32:30 2002 Page 5

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