GCMS calibration data for sample AE03265, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

. Data File : C:\MSDCHEM\1\DATA\031902\C 10 .D vial: 2 Acq On : 20 Mar 2002 4:15 pm Operator: McLean Sample : 10 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 22 08:42:27 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\1\5973N\5080302.M -(RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 15 0 159731.8 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 4114710 20.00 ug/L 0.00 17) Acenaphthene-diO 18.13 164 2218304 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.50 188 3496808 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 3167262 20.00 ug/L 0.00 44) Perylene-dl2 34.19 264 1722172 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.42 235 27984 0.67 ug/L 0.00 Spiked Amount 5.000 Recovery

Target Compounds “ . 13:40% Qvalue 2) N-nitroso-dimethyl amine 3.57 74 350162 9.76 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 653012 11.55 ug/L 98 4) 1,3 - Dichlorobenze 9.38 146 652185 11.66 ug/L 98 5) 1,4 - Dichlorobenzene 9.59 146 656604 11.77 ug/L 99 6) 1,2 - Dichlorobenzene 9.97 146 610152 11.82 ug/L 98 7) 2,2 ' - oxybis (1-Chloropr 10.43 45 1526422 11.85 ug/L 96 8) N-Nitroso-di -n-propylamine 10.77 70 492026 12.10 ug/L 96 9) Hexachloroethane 10.86 117 253145 12.08 ug/L 98 11) Nitrobenzene 11.11 77 763546 10.30 ug/L 97 12) Isophorone 11.82 82 1339507 9.82 ug/L 98 13) bis(2-Chloroethoxy) methan 12.55 93 856094 10.43 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 515325 10.94 ug/L 98 15) Naphthalene 13.08 12 8 1867074 10.92 ug/L 100 16) Hexachlorobutadiene 13.53 225 293457 11.14 ug/L 99 18) Hexachlorocyclopentadiene 15.61 237 156418 8.01 ug/L 92 19) 2-chloronaphthalene 16.51 162 1128638 11.15 ug/L 99 20) Dimethylphthalate 17.60 163 1272229 10.53 ug/L 98 21) 2,6-Dinitrotoluene 17.70 165 256085 9.95 ug/L 97 2 2) Acenaphthylene 17.70 152 1524203 10.85 ug/L 100 23) Acenaphthene 18.22 153 1047803 10.97 ug/L 96 24) 2,4-Dinitrotoluene 18.86 165 352975 9.58 ug/L 99 25) Diethylphthalate 19.74 149 1175184 11.30 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.89 2 04 607748 10.96 ug/L 98 27) Fluorene 19.76 166 1288788 11.45 ug/L 100 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 1573209 10.25 ug/L 98 30) N-Nitrosodiphenylamine 20.27 169 826272 10.99 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.32 248 356337 11.54 ug/L 94 32) Hexachlorobenzene 21.34 2 84 369241 11.34 ug/L 97 33) Phenanthrene 22.56 178 1825787 11.27 ug/L 100 34) Anthracene 22.70 178 1742706 10.84 ug/L 99 35) Di-n-butylphthalate 24.65 149 2022387 10.90 ug/L 100 36) Fluoranthene 26.06 ' 202 2042567 11.10 ug/L 98 39) Pyrene 26.69 202 2120302 9.68 ug/L 98 40) Butylbenzylphthalate 2 9.05 14 9 847626 9.04 ug/L 99 41) Benzo (a) antracene 30.29 22 8 1593029 9.58 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.91 149 1100792 8.88 ug/L 96 43) Chrysene 30.38 228 1664031 10.54 ug/L 99 45) Di-n-Octylphthalate 32.75 14 9 1657785 8.96 ug/L 100 46) Benzo (b) fluoranthene 33.23 252 1250964 10.31 ug/L 98

(#) = qualifier out of range (m) = manual integration CAL10C.D 5080302 .M Mon Mar 25 09:01:02 2002 Page 1

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