GCMS analysis results for sample AE03075, March 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report • Data File : C:\MSDCHEM\l\5973N\02FEB28\02715.D Vial: 5 Acq On : 28 Feb 2002 1:50 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 2 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 Pyrrolidine, 3-methyl- $$ 3... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.10 0.06 ug/L 26016 1, 4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrrolidine, 3-methyl- $$ 3-Meth... 85 C5H11N 034375-89-8 3 2 Azetidine, 1,2-dimethyl- 85 C5H11N 051764-32-0 3 3 4-METHYLPROPIOLACTAM 85 C4H7NO 000000-00-0 3 4 Phosphoramidous difluoride (CAS)... 85 F2H2NP 025757-74-8 2 Abundance Scan 64 (4.096 min): 02715.D (-) m/z 85.00 100.00% 43 85

5000 ....

0b • i • ■1 ■ i1 • • • i"■■i “ ■■i■ “ ■t• “ ■ i ■■1 17 55 mmmmmmmmmmmm m/z 3.80 4.00 43.10 4.20 4.40 98.19% m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3663: Pyrrolidine 3-methyl- $$ 3-Methylpyrrolidine 43

5000 85 V..AM. m/z 3.80 4.00 44.10 4.20 4.40 25.73% 15 2730 , 56 68 _____ 82 ob 11 > 11 > 1 ■ ■ > > ] I ■ > > । > > > 11 > > ] 11 > ■ i > । ■ < t 11 ■ > ^n/z~> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #3654: Azetidine, 1,2-dimethyl- > 42 _AAL 3.80 4.00 4.20 4.40 5000 m/z 51.00 14.54%

miz-> 5 ob 15

T 27 H 1 30 1 TTTTHH 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 56 1 ‘I' ‘‘ 70 TIampuuk '" 'i “ “ । 85 NMhAphpo (

Abundance #3610: 4-METHYLPROPIOLACTAM 4)2 ,jil. .jal.].. 3.80 4.00 4.20 4.40 m/z 49.00 9.42% 50001 WMMrWwi 85 27 39 0b mmH ’’’’I’1’A1+A++A’’’A1***’1*’**17’’1’/4 "' ■ i ■ ■" i iz—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 3.80 4.00 4.20 4.40

02715.D HP022102.M Fri Mar 01 10:07:07 2002 Page 5

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