GCMS surrogate recovery results for sample AE03184, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02MAR01\03184.D Vial: 4 Acq On : 1 Mar 2002 12:48 pm Operator: Sample : 508 scan Inst : Instrumen Misc : March 1, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library- : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 1 Acetonitrile, dichloro- Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 3.49 0.07 ug/L 24096 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetonitrile, dichloro- 109 C2HC12N 003018-12-0 83 2 1-Propyne, 3-chloro- (CAS) $$ Pr... 74 C3H3C1 000624-65-7 5 3 n-Butylamine-D9 82 C4H2D9N 000000-00-0 5 4 CHLOROPROPADIENE $$ 1,2-Propadie... 74 C3H3C1 003223-70-9 4 Abundance Scan 10 (3.487 min): 03184. D (-) m/z 74.00 100.00% 74

82 5000 47

51 3.50 3.60 3.70 3.80 3.90

m/z-> OT ■ ■ । 10 15 ■ 11 20 11 ■ ■ ■ ■ । ■ ■ > ■ । ■ ■ ■ ■ । ■ 25 30 35 44.1171... 40 45 50 55 60 65 70 75 ■ ■ i ■ ■ ■ ■ i' ■111'1 TTIB 80 i''111'' ■ ■ i 85 90 m/ z 82.00 53.89% Abundance #11644: Acetonitrile, dichloro- 74 35

5000 82 4 1.* I • 1-'' I«««111 11 11 3.50 3.60 3.70 3.80 3.90 88 47 m/z 83.90 32.98%

m/z-> On '' i " '' i " ' ‘ i " " i'1 10 + 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 111"111"1111111"' TT-p- 86 —T P AAMo Abundance #1928:1-Propyne, 3-chloro- (CAS) $$ Propargyl chloride $$... 74 3.50 3.60 3.70 3.80 3.90 5000 m/ z 47.00 32.45%

77 Oh

.AMMAN/., 1" i " " i " " i " " i n/z-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #1886: n-Butylamine-D9 33 3.50 3.60 3.70 3.80 3.90 82 m/ Z 76.00 31.75%

5000 30 46 20

m/z-> oh 10 15 20 111 ■ ■ 4l 42 *** 25 30 35 40 45 50 55 60 65 70 75 80 85 90 -mtpt TTI ! ' ' ' ’ I ‘ 3.50 3.60 3.70 3.80 3.90 ‘ ‘ I

'3184.D HP022102.M Mon Mar 04 12:32:52 2002 Page 3

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