DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C: \MSDCHEM\1\5973N\02FEB26\02017.D Vial: 5 Acq On : 26 Feb 2002 1:41 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 26, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102. M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 3-Hexanone (CAS) $$ Hexan-3... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

4.80 0.11 ug/L 53906 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Hexanone (CAS) 100 $$ Hexan-3-one ... C6H120 000589-38-8 83 2 3-Hexanone 100 C6H120 000589-38-8 83 3 3-Hexanone 100 C6H120 000589-38-8 83 4 3-Hexanone (CAS) $$ Hexan-3-one ... 100 C6H120 000589-38-8 83 Abundance Scan 126 (4.796 min): 02017.D (-) m/z 43.10 100.00% 43 57 71 5000 100 ■ I ■ ■ ■ i ■ i’i r । । । . 51 4.40 4.60 4.80 5.00 5.20

miz-> Of TTE1111111111111011111 Iglhaa i ■" ■ i ■'" i I " " I" " r " ' i' “ ■ i 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 m/z 57.00 99.49% Abundance #8261: 3-Hexanone (CAS) $$ Hexan-3-one $$ Ethyl propyl ket... 29 43 57

71 .. ............ 0 1 M. 5000 100 4.40 4.60 4.80 5.00 5.20 m/z 71.00 62.92%

miz-> O+ " I' ‘ " i' — m 85 —mmP '" i" " i " ■ ‘ I" " i ■ " 1111 TTTT 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #8252: 3-Hexanone 43 57 .D...... . r. , 4.40 4.60 4.80 5.00 5.20 29 71 5000 m/ z 100.00 32.53% 100

85 0! " i" ■ ■ i ■ 1p Hpt hpp 4 mt 1 11 mfe—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #8258:3-Hexanone 29 43 57 4.40 4.60 4.80 5.00 5.20 m/z 41.10 27.93% 71 5000 100

85 o " I " " i' — L —mmP -mmm WT - m/z- > 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 4.40 4.60 4.80 5.00 5.20

02017.D HP022102.M Wed Feb 27 08:34:39 2002 Page 5

NYC-WTC_000004573