VOCs GC/MS analysis results, Jan 17 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\02janl7\0117C10B.D Vial: 6 Acq On : 17 Jan 2002 2:21 pm Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Misc Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Jan 17 15:00 2002 Quant Results File: HP010702.RES

Quant Method : C:\HPCHEM\1\METHODS\HP010702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Thu Jan 10 08:57:29 2002 Response via : Initial Calibration DataAcq Meth : HP010702

Internal Standards R.T. Qlon Response Conc Units Dev(Min) ------------------------------------------------------------------------- 1) 1,4-DIFLUOROBENZENE 15.14 114 882310 5.00 ug/L -0.04 24) CHLOROBENZENE-D5 21.79 117 757088 5.00 ug/L -0.05 52) 1,4-DICHLOROBENZENE-D4 26.97 152 361238 5.00 ug/L -0.05

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.37 65 558839 4.88 -0.05 ug/L

Spiked Amount 5.000 Recovery = 97.60% 3) 4-BROMOFLUOROBENZENE 24.37 174 284973 4.77 -0.05 ug/L

Spiked Amount 5.000 Recovery = 95.40% 25) TOLUENE-D8 18.48 98 1072667 5.32 -0.05 ug/L

Spiked Amount 5.000 Recovery = 106.40%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.88 85 452189 11.69 100 ug/L

5) CHLOROMETHANE 5.50 50 458435 10.67 ug/L 92 6) VINYL CHLORIDE 5.62 62 437201 12.33 97 ug/L

7) BROMOMETHANE 6.61 94 309741 11.04 94 ug/L

8) CHLOROETHANE 6.75 64 281648 11.34 98 ug/L

9) TRICHLOROFLUOROMETHANE 7.32 101 794466 11.35 ug/L 98 10) Isopropyl Alcohol 7.99 45 1558 1.63 97 ug/L

11) 1,1,2-Trichloro-1,2,2-trif 8.20 101 376432 8.13 98 ug/L

12) ACETONE 8.29 43 90592 7.92 ug/L 99 13) 1,1-DICHLOROETHENE 8.64 61 591701 8.44 ug/L 96 14) METHYLENE CHLORIDE 9.63 49 730506 8.99 ug/L 98 15) METHYL TERT BUTYL ETHER 9.95 73 385192 8.12 ug/L 98 16) TRANS-I,2-DICHLOROETHENE 10.29 61 634729 9.14 ug/L 98 17) 1,1-DICHLOROETHANE 11.20 63 714648 9.37 ug/L

98 18) 2-BUTANONE (MEK) 12.04 43 123326 8.14 ug/L

94 19) 2,2-DICHLOROPROPANE 12.42 77 502399 9.41 ug/L 99 20) CIS-1,2-DICHLOROETHENE 12.51 96 379380 9.80 ug/L 98 21) CHLOROFORM 12.84 83 837850 9.61 ug/L 100 22) BROMOCHLOROMETHANE 13.22 49 406355 9.23 ug/L 97 23) 1,2-DICHLOROETHANE 14.56 62 659923 9.11 ug/L 99 26) 1,1,1-TRICHLOROETHANE 13.74 97 671979 9.74 ug/L 98 27) 1,1-DICHLOROPROPENE 14.06 75 565669 10.57 ug/L 98 28) CARBON TETRACHLORIDE 14.32 117 692485 9.98 ug/L

99 29) BENZENE 14.67 78 1412532 10.18 ug/L

100 30) TRICHLOROETHENE 15.94 95 434125 10.20 ug/L

97 31) 1,2-DICHLOROPROPANE 16.29 63 396624 9.95 ug/L 96 32) DIBROMOMETHANE 16.97 174 171299 9.73 ug/L 98 33) BROMODICHLOROMETHANE 16.81 83 592016 10.05 ug/L 96 ------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration 0117C10B.D HP010702.M Thu Jan 17 15:00:09 2002 Page, 1

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