VOCs GC/MS analysis results, Jan 14 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\02jan14\0114C10.D Vial: 2 Acq On : 14 Jan 2002 9:14 am Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Misc : January 14, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Jan 14 9:52 2002 Quant Results File: HP010702.RES

Quant Method : C:\HPCHEM\1\METHODS\HP010702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Thu Jan 10 08:57:29 2002 Response via : Initial Calibration DataAcq Meth : HP010702

Internal Standards R.T. Qlon Response Conc Units Dev(Min) ------------------------------------------------------------------------- 1) 1,4-DIFLUOROBENZENE 15.10 114 766324 5.00 ug/L -0.07 24) CHLOROBENZENE-D5 21.74 117 669779 5.00 ug/L -0.11 52) 1,4-DICHLOROBENZENE-D4 26.92 152 345299 5.00 ug/L -0.11

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.34 65 540562 5.43 ug/L -0.09 Spiked Amount 5.000 Recovery = 108.60% 3) 4-BROMOFLUOROBENZENE 24.34 174 260330 5.01 ug/L -0.09 Spiked Amount 5.000 Recovery = 100.20% 25) TOLUENE-D8 18.45 98 907289 5.08 ug/L -0.09 Spiked Amount 5.000 Recovery = 101.60%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 481860 14.35 ug/L 98 5) CHLOROMETHANE 5.50 50 383691 10.29 ug/L 100 6) VINYL CHLORIDE 5.59 62 353683 11.48 ug/L 95 7) BROMOMETHANE 6.58 94 245716 10.09 ug/L 97 8) CHLOROETHANE 6.71 64 233280 10.81 ug/L 99 9) TRICHLOROFLUOROMETHANE 7.28 101 688997 11.33 ug/L 99 10) Isopropyl Alcohol 7.87 45 868728 1048.50 ug/L 99 11) 1,1,2-Trichloro-1,2,2-trif 8.17 101 455269 11.32 ug/L 95 12) ACETONE 8.24 43 108188 10.89 ug/L 99 13) 1,1-DICHLOROETHENE 8.60 61 701103 11.51 ug/L 97 14) METHYLENE CHLORIDE 9.60 49 714809 10.13 ug/L 98 15) METHYL TERT BUTYL ETHER 9.91 73 440250 10.69 ug/L 99 16) TRANS-I,2-DICHLOROETHENE 10.28 61 674442 11.18 ug/L 92 17) 1,1-DICHLOROETHANE 11.17 63 748838 11.31 ug/L 99 18) 2-BUTANONE (MEK) 12.00 43 139896 10.73 ug/L 98 19) 2,2-DICHLOROPROPANE 12.38 77 522064 11.26 ug/L 100 20) CIS-1,2-DICHLOROETHENE 12.47 96 383163 11.40 ug/L 97 21) CHLOROFORM 12.80 83 857507 11.33 ug/L 99 22) BROMOCHLOROMETHANE 13.19 49 424017 11.09 ug/L 93 23) 1,2-DICHLOROETHANE 14.53 62 706392 11.23 ug/L 97 26) 1,1,1-TRICHLOROETHANE 13.71 97 696710 11.41 ug/L 95 27) 1,1-DICHLOROPROPENE 14.02 75 563873 11.91 ug/L 99 28) CARBON TETRACHLORIDE 14.28 117 718234 11.70 ug/L 94 29) BENZENE 14.63 78 1452680 11.83 ug/L 99 30) TRICHLOROETHENE 15.90 95 432703 11.49 ug/L 97 31) 1,2-DICHLOROPROPANE 16.25 63 385626 10.94 ug/L 97 32) DIBROMOMETHANE 16.93 174 175190 11.24 ug/L 92 33) BROMODICHLOROMETHANE 16.78 83 599634 11.50 ug/L 96 ------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration 0114C10.D HP010702.M Mon Jan 14 09:52:44 2002 Page 1

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