E-mails 2002 M. Gilsenan

NYC 9/11 Public Portal Document

Cahill said the very fine particles contained high levels of sulfur and sulfur-based compounds, which in early analyses appear to have been dominated by sulfuric acid. The very fine particles also contain high levels of very fine silicon, potentially from the thousands of tons of glass in the debris. Cahill noted that even those large amounts were likely to be smaller than those present at Ground Zero and some other parts of Lower Manhattan, since weather data show that typically only part of the dust clouds traveled directly over the sampling site. "Even on the worst air days in Beijing, downwind from coal-fired power plants, or in the Kuwaiti oil fires, we did not see these levels of very fine particulates," Cahill said. The amounts of very fine particles, particularly very fine silicon, decreased sharply during the month of October. Coarse particles Similar to the high concentrations of very fine particles, virtually all the air samples from the trade center site carried high concentrations of coarse particles — those about 12 micrometers to 5 micrometers in diameter. "These particles simply should not be there," Cahill said. "It had rained, sometimes heavily, on six days in the prior three weeks. That rain should have settled these coarse particles." The finding suggests that coarse particles were being continually generated from the hot debris pile. This observation is at least qualitatively supported, for while they are still being analyzed, the coarse particles appear to be coated with combustion products, including soot, Cahill said. Metals Many different metals were found in the samples of very fine particles, and some were found at the highest levels ever recorded in air in the United States. However, there are few established safety guidelines for airborne metals. One metal for which there is a guideline, lead, was present at low levels in fine and very fine particles. Some of the metals for which there are no guidelines that were present in very fine particles in relatively high concentrations were iron, titanium (some associated with powdered concrete), vanadium and nickel (often associated with fuel-oil combustion), copper and zinc. Mercury was seen occasionally in fine particles but at low concentrations. Many of those metals are widely used in building construction, wiring and plumbing. Some are common in computers. The metal content of the coarse particles is still being analyzed. Asbestos and glass Although some asbestos was used in the buildings for fireproofing and in floor tiles, and the DELTA group checked for it carefully using the electron microscope, they found very few asbestos fibers, even in the very fine particles. Some particles that appeared to be glass were seen, but they were not in the form of long shards, which can mimic asbestos fibers. Clean-up recommendations All evidence indicates that ambient air in New York City now is little influenced by the World Trade Center collapse, especially since the 4

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