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GC/MS analysis results for sample AD22976, Oct 2001

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Laboratory report documenting GC/MS analysis of sample AD22976 conducted on October 15, 2001, identifying unknown compounds.

NYC-WTC_000087863–000087874

Folder label: “GC/MS Scan 9/21/01

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NYC 9/11 Public Portal Document yuanuicacion Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\OCT1101\22976.D Vial: 7 Acq On : 11 Oct 2001' 3:37 pm Operator: 2 09 GTkLOS Sample : reinject Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Oct 11 16:25 2001 Quant Results File: NP091101.RES Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Last Update : Thu Sep 13 12:47:04 2001 Response via : Initial Calibration DataAcq Meth : NP091101

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 11.76 152 507731 20.00 ug/1 -0.15 19) Naphthalene-d8 15.38 136 1998714 20.00 ug/1 -0.15 31) Acenaphthene-dlO 20.66 164 973194 20.00 ug/1 -0.16 49) Phenanthrene-dlO 25.08 188 1383810 20.00 ug/1 -0.16 59) Chrysene-dl2 33.12 240 1020220 20.00 ug/1 -0.16 68) Perylene-dl2 37.24 264 761069 20.00 ug/1 -0.18

System Monitoring Compounds 4) 2-Fluorophenol 0.00 112 0 0.00 ug/1 Spiked Amount 75.000 Recovery = 0.00% 5) Phenol-d5 0.00 99 0 0.00 ug/1 Spiked Amount 75.000 Recovery = 0.00% 6) 2-Chlorophenol-d4 11.76 132 304 0.01 ug/1 0.35 Spiked Amount 75.000 Recovery = 0.01% 7) 1,2-Dichlorobenzene-d4 12.27 152 5378 0.22 ug/1 -0.16 Spiked Amount 50.000 I Recovery = 0.44% 20) Nitrobenzene-d5 0.00 82 0 0.00 ug/1 Spiked Amount 50.000 Recovery = 0.00% 32) 2-Fluorobiphenyl 18.80 172 2465 0.04 ug/1 0.00 Spiked Amount 5'0.000 Recovery = 0.08% 33) 2,4,6-Tribromophenol 0.00 330 0 0.00 ug/1 Spiked Amount 75.000 Recovery = 0.00% 62) Terphenyl-dl4 29.98 244 2157 0.04 ug/1 -0.17 Spiked Amount 50.000 Recovery = 0.08% Target Compounds Qvalue 2) Pyridine 5.14 79 310 N.D. 3) N-nitroso-dimethyl amine 0.00 74 0 N.D. 8) Phenol 0.00 94 0 n'.d. 9) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 10) 2-Chlorophenol 0.00 128 0 N.D. 11) 1,3-Dichlorobenzene 1 0.00 146 0 N.D. 12) 1,4-Dichlorobenzene 0.00 146 0 N.D. 13) 1,2-Dichlorobenzene 0.00 146 0 N.D. 14) 2-Methylphenol 0.00 108 0 N.D. 15) 2,2'-oxybis(1-Chloropropan 0.00 45 0 N.D. 16) 3 &:4-Methylphenol 0.00 108 0 N.D. 17) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 18) Hexachloroethane I 0.00 117 0 N.D. 21) Nitrobenzene 0.00 77 0 N.D. 22) Isophorone 14.10 82 399 N.D. (#) = qualifier out of range (m) = manual integration 22976.D NP091101.M Moh Oct 15 08:39:01 2001 Page 1

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