VOC analysis results, sample AE11905, May 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\02MAY22\12157S.D Vial 1 Acq On 22 May 2002 3:35 pm Operator 201-wb Sample nyc spk 20 Inst GC/MS Ins Mise Multiplr 1.00 MS Integration Params: GAS6.P Quant Time: Jun 3 14:24 2002 Quant Results File: HP051702.RES

Quant Method : C:\HPCHEM\1\METHODS\HP051702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Fri May 31 11:43:42 2002 Response via : Initial Calibration DataAcq Meth : HP051702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.03 114 1070643 5.00 ug/L 0.00 24) CHLOROBENZENE-D5 21.71 117 966758 5.00 ug/L 0.00 52) 1,4-DICHLOROBENZENE-D4 26.88 152 498227 5.00 ug/L 0.00

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.27 65 454150 4.34 ug/L 0.00 Spiked Amount 5.000 Recovery = 86.80% 3) 4-BROMOFLUOROBENZENE 24.30 174 390365 5.17 ug/L 0.00 Spiked Amount 5.000 Recovery = 103.40% 25) TOLUENE-D8 18.41 98 1286238 4.87 ug/L 0.00 Spiked Amount 5.000 Recovery = 97.40%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.82 85 735310 16.47 ug/L 99 5) CHLOROMETHANE 5.34 50 1250675 19.51 ug/L 98 6) VINYL CHLORIDE 5.54 62 474113 15.27 ug/L 100 7) BROMOMETHANE 6.53 94 481169 21.76 ug/L 97 8) CHLOROETHANE 6.68 64 652734 20.39 ug/L 100 ■ 9) TRICHLOROFLUOROMETHANE 7.23 101 1089017 18.18 ug/L 98 12) ACETONE 8.19 43 429475 45.30 ug/L 96 13) 1,1-DICHLOROETHENE 8.55 61 1505170 19.56 ug/L 99 14) METHYLENE CHLORIDE 9.55 49 1445109 20.59 ug/L • 97 15) METHYL TERT BUTYL ETHER 9.86 73 1058415 19.46 ug/L 97 16) TRANS-1,2-DICHLOROETHENE- 10.22 61 1773981 22.74 ug/L 94 17) 1,1-DICHLOROETHANE 11.10 63 1923123 22.76 ug/L 98 18) 2-BUTANONE (MEK) 11.94 43 592613 83.22 ug/L 96 19) 2,2-DICHLOROPROPANE 12.33 77 1553002 22.66 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.41 96 1014949 22.14 ug/L 97 21) CHLOROFORM 12.75 83 1945364 21.52 ug/L 97 22) BROMOCHLOROMETHANE 13.13 49 779299 21.91 ug/L 96 23) 1,2-DICHLOROETHANE 14.47 62 1323775 19.59 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.64 97 1568238 19.95 ug/L 100 27) 1,1-DICHLOROPROPENE 13.96 75 1598858 21.84 ug/L 100 28) CARBON TETRACHLORIDE 14.23 117 1335256 20.64 ug/L 99 29) BENZENE 14.57 78 3567430 22.57 ug/L 100 30) TRICHLOROETHENE 15.85 95 .1117353 21.21 ug/L 99 31) 1,2-DICHLOROPROPANE 16.21 63 916212 21.48 ug/L 98 32) DIBROMOMETHANE 16.87 174 402988 19.49 ug/L 100 33) BROMODICHLOROMETHANE 16.72 83 1294687 20.87 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.20 63 303821 36.94 ug/L 99 35) METHYL ISO-BUTYL KETONE 17.28 58 466675 87.33 ug/L 99 36) CIS-1,3-DICHLOROPROPENE 17.81 75 1265853 21.08 ug/L 98 37) TOLUENE 18.58 91 3623479 22.46 ug/L 97 38) TRANS-1,3-DICHLOROPROPENE 18.85 75 948184 19.43 ug/L 100 39) 1,1,2-TRICHLOROETHANE 19.24 97 480915 19.35 ug/L . 99 40) TETRACHLOROETHENE 20.02 166 1057179 22.23 ug/L ■ 97 41) 1,3-DICHLOROPROPANE 19.77 76 957286 19.84 ug/L 97 42) DIBROMOCHLOROMETHANE 20.45 129 640619 21.31 ug/L 96 43) 1,2-DIBROMOETHANE 20.91 107 491362 18.99 ug/L 100 44) CHLOROBENZENE 21.79 112 2161331 22.12 ug/L 98 45) 1,1,1,2-TETRACHLOROETHANE 21.83 131 752156 19.93 ug/L 97 46) 2-HEXANONE 19.12 43 861999 84.28 ug/L 100 47) ETHYLBENZENE 21.83 91 4313834 22.70 ug/L 100 48) P & M-XYLENE 21.98 106 2806918 46.02 ug/L 100

(#) = qualifier out of range (m) = manual integration 12157S.D HP051702.M Mon Jun 03 14:25:00 2002 Page 1

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