GCMS reference standard results for sample AE06049, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\040502\REFA0405.D Vial: 5 Acq On 5 Apr 2002 11:43 pm Operator: Bohlk Sample REFl 3/15/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 08 05:38:28 2002 Quant Results File: 5080402.RES

Quant Method : C:\MSDCHEM\l\5973N\5080402.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Fri Apr 05 05:56:22 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 9.46 152 1500148 20.00 ug/L -0.01 10) Naphthalene-d8 12.94 136 6645059 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.06 164 3722158 20.00 ug/L 0.00 29) Phenanthrene-dlO 22.42 188 5364496 20.00 ug/L 0.00 38) Chrysene-dl2 30.25 240 4187783 20.00 ug/L 0.00 44) Perylene-dl2 34.12 264 2380057 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ODD (SURR) 27.36 235 218307 4.10 ug/L 0.00 Spiked Amount 5.000 Recovery = 82.00%.

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.54 74 266614m 4.66 ug/L 3) bis(2-chloroethyl) ether 8.90 93 681245 8.17 ug/L 83 4) 1,3 - Dichlorobenze 9.29 146 477643 6.33 ug/L 98 5) 1,4 - Dichlorobenzene 9.51 146 486768 6.60 ug/L 98 6) 1,2 - Dichlorobenzene 9.88 146 435726 6.35 ug/L 99 7) 2,2 ' - oxybis (l-Chloropr 10.35 45 1110517 8.63 ug/L 93 8) N-Nitroso-di-n-propylamine 10.67 70 523073 8.24 ug/L 96 9) Hexachloroethane 10.77 117 171729 6.06 ug/L 93 11) Nitrobenzene 11.02 77 614213 5.81 ug/L 95 12) Isophorone 11.73 82 1479052 7.74 ug/L 96 13) bis(2-Chloroethoxy) methan 12.47 93 875184 7.56 ug/L 99 14) 1,2,4-Trichlorobenzene 12.82 180 390967 6.80 ug/L 99 15) Naphthalene 12.99 128 1864902 8.13 ug/L 99 16) Hexachlorobutadiene 13.44 225 149815 5.26 ug/L 97 18) Hexachlorocyclopentadiene 15.52 237 25442 1.27 ug/L 82 19) 2-chloronaphthalene 16.42 162 906262 7.06 ug/L 99 20) Dimethylphthalate 17.52 163 1307504 8.74 ug/L 98 21) 2,6-Dinitrotoluene 17.62 165 214733 6.79 ug/L 97 22) Acenaphthylene 17.60 152 1409353 7.99 ug/L 99 23) Acenaphthene 18.14 153 1058523 8.47 ug/L 99 24) 2,4-Dinitrotoluene 18.77 165 236590 5.44 ug/L 91 25) Diethylphthalate 19.64 149 1254087 9.94 ug/L , 99 26) 4-Chlorophenyl-phenyl ethe 19.81 204 529868 8.13 ug/L 98 27) Fluorene 19.67 166 1299401 9.13 ug/L 97 28) Azobenzen/ 1,2-Diphenylhyd 20.26 77 1819347 8.10 ug/L 92 30) N-Nitrosodiphenylamine 20.18 169 664065 7.05 ug/L . 97 31) 4-Bromophenyl-phenyl ether 21.23 248 266428 8.31 ug/L 92 32) Hexachlorobenzene 21.26 284 264777 8.58 ug/L 84 33) Phenanthrene 22.47 178 1826135 9.23 ug/L 99 34) Anthracene 22.62 178 1637552 8.51 ug/L 99 35) Di-n-butylphthalate 24.58 149 2135343 9.53 ug/L 99 36) Fluoranthene 25.98 202 1883275 9.13 ug/L 85 39) Pyrene 26.61 202 1963326 8.02 ug/L 85 40) Butylbenzylphthalate 28.98 149 787960 7.43 ug/L 85 41) Benzo (a) antracene 30.21 228 1294669 7.72 ug/L 100 42) Bis (2-ethylhexyl) phthala 30.85 149 1119596 8.20 ug/L 98 43) Chrysene 30.31 228 1376091 8.56 ug/L 98 45) Di-n-Octylphthalate 32.70 149 1374730 6.03 ug/L 97 46) Benzo (b) fluoranthene 33.16 252 961423 7.47 ug/L 92

(#) = qualifier out of range (m) = manual integration REFA0405.D 5080402.M Mon Apr 08 05:40:08 2002 Page 1

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