GCMS calibration results, sample AE05515, April 2002

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Quantitation Ri •t (QT Reviewed)

j Data File C:\HPCHEM\1\DATA\APRO10 2\C ,2 5 Vial: 2 ‘ Acq On 1 Apr 2002 12:11 pm Operator: Sample : Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 4 12:08 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.26 152 743415 20.00 ug/1 -0.09 10) Naphthalene-d8 15.90 136 3378263 20.00 ug/1 -0.09 17) Acenaphthene-dlO 21.21 164 1877843 20.00 ug/1 -0.10 29) Phenanthrene-dlO 25.65 188 2825658 20.00 ug/1 -0.11 38) Chrysene-dl2 33.71 240 1602040 20.00 ug/1 -0.13 44) Perylene-dl2 37.95 264 786078 20.00 ug/1 -0.17

System Monitoring Compounds 37) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = ,^.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.89 74 613669 24.33 ug/1 # 70 3) bis(2-Chloroethyl)ether 11.67 93 1147734 28.26 ug/1 90 4) 1,3-Dichlorobenzene 12.16 146 1099880 26.21 ug/1 99 5) 1,4-Dichlorobenzene 12.30 146 1115237 26.51 ug/1. 100 6) 1,2-Dichlorobenzene 12.82 146 1082650 27.59 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.14 45 1572290 27.51 ug/1 99 8) N-Nitroso-di-n-propylamine 13.54 70 780276 29.53 ug/1 # 86 9) Hexachloroethane 13.66 117 415688 26.44 ug/1 95 11) Nitrobenzene 13.96 77 1146593 24.83 ug/1 90 12) Isophorone 14.60 82 2190618 25.01 ug/1. 99 13) bis(2-Chloroethoxy)methane 15.28 93 1452832 25.35 ug/1 98 14) 1,2,4-Trichlorobenzene 15.78 180 1055037 26.61 ug/1 96 15) Naphthalene 15.96 128 3293269 26.37 ug/1 99 16) Hexachlorobutadiene 16.49 225 546637 27.65 ug/1 100 18) Hexachlorocyclopientadiene 18.68 237 326045 25.64 ug/1 98 19) .2-Chloronaphthalene 19.47 162 2069394 25.67 ug/1 95 20) Dimethylphthalate 20.56 163 2420948 25.62 ug/1 99 21) 2,6-Dinitrotoluene 20.78 165 581219 25.34 ug/1 # 80 22) Acenaphthylene 20.73 152 2904327 25.20 ug/1 99 23) Acenaphthene 21.30 153 2047414 25.42 ug/1 98 24) 2,4-Dinitrotoluene 21.94 165 756085 24.64 ug/1 # 76 25) Diethylphthalate 22.70 149 2282507 24.88 ug/1 96 26) 4-Chlorophenyl-phenylether 22.83 204 1048888 26.70 ug/1 93 27) Fluorene 22.83 ' 166 2202896 25.86 ug/1 99 28) Azobenzeh/ 1,2-Diphenylhyd 23.31 77 2210179 22.48 ug/L # 83

(#) = qualifier out of range (m) = manual integration CAL25.D GCMS0403.M Thu Apr 04 12:09:22 2002 Page 1

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