GCMS calibration table for TCLP analysis, February 2002

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Data File : C:\HPCHEM\l\DATA\FEB1402\1004.D Vial: 10 Acq On : 14 Feb 2002 6:47 pm Operator: 209 GALOS Sample : GC/MS SCAN 1/15 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 19 12:57 2002 Quant < Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title Last Update Response via DataAcq Meth : : : : 209 625/TCLP calibration table Wed Feb 13 11:43:23 2002 Initial Calibration GCMS0208 J Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.35 152 301549 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1166777 20.00 ug/1 0.00 17) Acenaphthene-diO 21.31 164 627591 20.00 ug/1 0.00 29) Phenanthrene-dlO 25.75 188 917744 20.00 ug/1 -0.02 38) Chrysene-dl2 33.82 240 640591 20.00 ug/1 -0.03 44) Perylene-dl2 38.11 264 409054 20.00 ug/1 -0.02

System Monitoring Compounds 37) 2,4-DDD 30.83 235 52754 5.73 ug/mL 0.33 Spiked Amount 5.000 Recovery = 114.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 0.00 74 0 N.D. 3) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,21-oxybis(1-Chloropropan 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy)methane 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 16.04 128 222 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. 22) Acenaphthylene 0.00 152 0 N.D. 2 3) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 22.78 149 414 N.D. 26) 4-Chlorophenyl-phenylether 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 28) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D.

(#) = qualifier out of range (m) = manual integration 1004.D GCMS0308.M Thu Mar 14 15:26:18 2002 Page 1

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