GCMS method 508 calibration data sheet, Feb 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File : C:\MSDCHEM\1\DATA\022102\CAL1.D Vial: 3 Acq On : 21 Feb 2002 4:58 pm Operator: McLean Sample : 5 MIX Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Feb 27 06:05:39 2002 'Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 9.58 150 935554 20.00 ug/L 0.00 10) Naphthalene-d8 13.05 136 2419784 20.00 ug/L 0.00 17) Acenaphthene-diO 18.17 164 1318240 20.00 ug/L 0.00 29) Phenanthrene-diO 22.53 188 2004536 20.00 ug/L 0.00 38) Chrysene-dl2 30.34 240 1825452 20.00 ug/L -0.02 44) Perylene-dl2 34.21 264 1365306 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.47 235 20277 0.64 ug/L 0.00 Spiked Amount 5.000 Recovery = 12.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.61 74 131210 4.64 ug/L 100 3) bis(2-chloroethyl) ether 9.02 93 279835 6.32 ug/L 100 4) 1,3 - Dichlorobenze 9.41 146 254859 6.09 ug/L 98 5) 1,4 - Dichlorobenzene 9.62 146 255013 6.14 ug/L 99 6) 1,2 - Dichlorobenzene 10.00 146 241803 6.28 ug/L 99 7) 2,2 ' - oxybis (l-Chloropr 10.46 45 679339 6.34 ug/L 99 8) N-Nitroso-di-n-propylamine 10.79 70 196036 5.77 ug/L 98 9) Hexachloroethane 10.89 117 100258 5.97 ug/L 99 11) Nitrobenzene 11.14 77 318352 5.64 ug/L 99 12) Isophorone 11.85 82 547585 5.32 ug/L 98 13) bis(2-Chloroethoxy) methan 12.59 93 352505 5.65 ug/L 96 14) 1,2,4-Trichlorobenzene 12.94 180 199666 5.80 ug/L 98 15) Naphthalene 13.11 128 766075 6.02 ug/L 99 16) Hexachlorobutadiene 13.56 225 112814 5.90 ug/L 98 18) Hexachlorocyclopentadiene 15.64 237 44726 3.47 ug/L 98 19) 2-chloronaphthalene 16.55 162 441086 5.85 ug/L 99 20) Dimethylphthalate 17.62 163 490266 5.46 ug/L 99 21) 2,6-Dinitrotoluene 17.72 165 88311 4.82 ug/L 90 22) Acenaphthylene 17.72 152 601482 5.81 ug/L 98 23) Acenaphthene 18.25 153 436386 6.07 ug/L 95 24) 2,4-Dinitrotoluene 18.88 165 120444 4.57 ug/L 84 25) Diethylphthalate 19.77 149 469432 6.10 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.93 204 232449 5.81 ug/L 99 27) Fluorene 19.78 166 509661 6.22 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.38 77 665548 5.66 ug/L 98 30) N-Nitrosodiphenylamine 20.30 169 317699 5.94 ug/L 98 31) 4-Bromophenyl-phenyl ether 21.35 248 125159 5.91 ug/L 98 32) Hexachlorobenzene 21.37 284 130135 5.97 ug/L 94 33) Phenanthrene 22.59 178 709512 6.11 ug/L 99 34) Anthracene 22.73 178 664052 5.95 ug/L 99 35) Di-n-butylphthalate 24.68 149 758167 5.65 ug/L 99 36) Fluoranthene 26.09 202 775203 5.80 ug/L 97 39) Pyrene 26.71 202 804795 5.42 ug/L 99 40) Butylbenzylphthalate 29.08 149 283678 4.46 ug/L 93 41) Benzo (a) antracene 30.31 228 601548 5.02 ug/L 98 42) Bis (2-ethylhexyl) phthala 30.95 149 374120 4.52 ug/L 99 43) Chrysene 30.40 228 662227 5.67 ug/L 99 45) Di-n-Octylphthalate 32.79 149 547362 3.91 ug/L 97 46) Benzo (b) fluoranthene 33.26 252 577879 5.06 ug/L 99

(#) = qualifier out of range (m) = manual integration CALl.D 5080202.M Wed Feb 27 06:05:43 2002 Page 1

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